Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
Brunquell, a German manufacturer, has criticised the present method
of conducting operations, and proposes that it is necessary as far
as practicable to aid the secondary formation of cyanogen by ammonia
and incandescent charcoal, and to avoid loss of potash by using pure
animal substances, and preventing contact with the solid products of
combustion from the furnace. With this view he adopts a horizontal
reverberatory furnace, the hearth of which is a cast-iron tray about
4½ ft. long, 4 ft. wide, and 3½ in. deep. The crown of the furnace is
built as flat as possible, the working space is limited, and the charge
is kept from contamination by the fire. Such a furnace, despite certain
drawbacks, presents important advantages. Fuel is economised; the
process is hastened so that seven or eight charges can be dealt with
in a day, instead of only four; and the furnaces cost less and endure
longer. The charge consists of 220 lb. potash, of which two-thirds is
from evaporated mother-liquors, and one-third fresh; 44 lb. animal
charcoal from the carbonisation of substances poor in nitrogen; 140-150
lb. of pure animal matters as dry as practicable; and 17½ lb. iron. The
firing is urged and the charge is stirred till all the potash is fused,
when the ash-pit is closed, and the damper turned on for charging half
the animal charcoal. The firing and stirring are again pushed on till
the proper consistency is attained, and potassium vapour begins to burn
off. In this state the mass is ready to receive the animal
[Illustration: Figs. 14, 15, 16, 17.--YELLOW PRUSSIATE
FURNACE.]
substances, those rich in nitrogen being first added in small portions
at a time. Their effect is to render the mass hard, dry, and difficult
of fusion, whereupon the remainder of the animal charcoal should be
promptly introduced. After thorough agitation, the working door is
closed for a short time, and the contents of the furnace are rapidly
discharged into a covered iron pan.
The character of the animal matters employed varies so much that it is
impossible to lay down hard and fast rules for the proportions of the
several ingredients, or the duration of the roasting. Nor is the value
of a raw material always in proportion to its richness in nitrogen,
because the poorer material may waste less potash, consume less fuel,
and require less labour. The addition of iron filings or turnings is
useful only in prolonging the life of the cast-iron crucibles.
_Combination of the Cyanide and Iron Solutions._--A great number of
recipes are in vogue for combining the two solutions of ferrocyanide
and an iron salt, both with reference to their proportions, and to the
addition of foreign matters of various kinds. These variations in the
formulæ give rise to distinct names for some kinds of Prussian blue,
which will be referred to below. The ordinary common Prussian blue has
a greenish tendency, and is chiefly made according to one or the other
of the following directions:--
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