Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
(1) Mix a solution of 100 lb. yellow prussiate with a solution of 100
lb. green copperas (ferrous sulphate) and 18 lb. alum, to which 9 lb.
sulphuric acid has been added, and let the mixture stand for 2-3 hours,
or until the solid portion has completely settled out. Decant the clear
supernatant liquor, and well wash the precipitate with clean waters.
Finally throw it on a filter and subject it to repeated disturbance,
so as to ensure the admission of air to every particle, in order that
the requisite oxidation may take place. The proportion of alum used
is subject to very great variation according to individual fancy; it
renders the subsequent grinding of the pigment a very much easier
matter, but it causes the shade of blue to be paler than it otherwise
would be.
(2) The simple solutions of green copperas and yellow prussiate in
equal proportions are mixed together without any other ingredient being
added, and the precipitate produced is washed, filtered, and aërated as
in (1). It is, however, inferior by reason of the oxide of iron formed
in the pigment spoiling the purity of the colour, and necessitating the
treatment of the wet mass with hydrochloric acid, at some expense, for
removal of the iron oxide.
ANTWERP BLUE.--This pale variety of Prussian blue has but
little importance now. It is prepared by adding a solution of 4 lb.
yellow prussiate in 5-6 gallons of water to one of 2 lb. sulphate
of iron, and 1 lb. each of alum and sulphate of zinc in an equal
quantity of water. The resulting pigment consists of a mixture of the
ferrocyanides of iron, alumina, and zinc; it is washed, filtered,
aërated, and dried as other forms of Prussian blue.
BONG’S BLUE.--When cyanide of potassium is added to an
acid solution of a copper salt, a red colour is produced, which has
already been mentioned by different observers. The substance formed
is very changeable, at least in the liquid where it is formed. It
is decomposed by acids, alkalies, cyanide of potassium, and even
decomposes spontaneously, the colour changing to yellow. It is
precipitated by insoluble cyanides; hence when a dilute acid is added
to the red solution, the dye is at once thrown down along with the
cyanide of copper. If the precipitate thus obtained is treated with
sulphuretted hydrogen, it is decomposed and the substance is set free.
This substance can combine with iron, like cyanogen, so as to conceal
the properties of the iron. This compound is very permanent, and has
lately been studied by Bong, who gives the following directions for its
preparation:--
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