Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
Deep. (1) 1 cwt. barytes, 5 lb. green copperas, 5 lb. yellow
prussiate.
Deep. (2) 1 cwt. china clay, 10 lb. green copperas, 10 lb. yellow
prussiate.
Deep. (3) 1 cwt. gypsum, 7½ lb. green copperas, 7½ lb. yellow
prussiate.
In each case about 50-60 gallons of water are required.
To determine the amount of barytes present in a sample, boil about 50
gr. with caustic soda, filter, wash the residue free from soda, treat
with sulphuric acid, well wash the insoluble residue, dry, and weigh.
CHINESE BLUE.--This well-known and favourite form of Prussian
blue is prepared with great care, and is usually sold in fine powder
or little cubes. Its composition is virtually identical with that
of ordinary Prussian blue, but it is more free from impurities, and
shows a fine bronze bloom or lustre on newly fractured surfaces. Being
pure, it is entirely dissolved by oxalic acid; and its composition
is about 52 per cent. oxide of iron, 43½ cyanogen, and 4½ water. In
dyeing and calico-printing it is extensively employed. Its tint varies
from greenish to violet, according to modifications in the method of
manufacture, the chief difference being that yellow prussiate gives a
greenish tone and red prussiate a violet.
The process of preparation is mainly as follows. In about 40 gallons
of cold water dissolve 1 cwt. of green copperas selecting it carefully
for freedom from insoluble oxide; add about 5 pints of sulphuric acid.
This liquor very rapidly undergoes oxidation, by which oxide of iron
is thrown down, and the solution is rendered unfit for making the best
quality pigment. Therefore it should be prepared only immediately
before it is used. In another vessel containing about 40 gallons of
cold water, dissolve 1 cwt. of yellow prussiate (if a green shade is
desired), or of red prussiate (if a violet tint is wished for). Even
larger quantities of water may be used for the solutions, as the more
dilute they are the finer is the colour precipitated and the greater
the lustre on the surface of the finished pigment.
When the two solutions of yellow or red prussiate and acidified green
copperas are brought together, a bluish-white precipitate is thrown
down. This is allowed to completely separate itself, and then the clear
supernatant liquid is drawn off.
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