Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
This substance is likewise precipitated by salts of zinc, mercury, and
silver. All these precipitates are pink or purple, very beautiful, and
of remarkable brilliancy. They are soluble in alkalies. Iron salts
yield no precipitate, nor do lead salts, except in the presence of
ammonia, when a blue-violet precipitate is formed. When treated with
sulphuretted hydrogen, these precipitates yield purple-red and acid
liquids, which undergo change in the air, especially if warm, forming
Prussian blue. When these liquids are neutralised with alkali, purple
compounds are formed, which are permanent in the air, soluble in water,
slightly so in alcohol, and insoluble in ether. Their colouring power
is exceptionally great. These pigments will unite with ferrocyanides,
and in its preparation such a compound is produced in considerable
quantity; it is likewise of a purple colour, and gives a rose-coloured
precipitate with acetate of lead. Both alone and in this compound it is
very permanent; it resists the action of sulphurous acid, concentrated
and boiling alkalies, and dilute acids, but is rapidly destroyed by
chlorine and nitric acid. If this pigment could be prepared cheaply
enough, it would probably be used with advantage in the arts, on
account of its resistance to chemical reagents and light, the variety
of its shades, and its brilliancy. It does not colour fibres directly,
but can readily be fixed on them from slightly acid solutions, if they
are previously mordanted with metallic oxides.
BRUNSWICK BLUE.--This pigment is made in pale, medium, and
deep shades, and is an extremely useful colour, being very fine,
requiring no grinding, thoroughly permanent in light and air, hardly
acted upon by acids, but turned brown by alkalies, and liable on
standing to separate into two portions--a white and a blue--the latter
coming to the surface while the former sinks, and necessitating a
thorough stirring of the paint before use.
It generally consists simply of barytes, or gypsum, or china clay,
coloured by a small percentage of Prussian blue, with or without the
addition of a lesser proportion of ultramarine. The barytes or other
base is very thoroughly agitated in water, while a solution of green
copperas and a solution of yellow prussiate are gradually added without
ceasing the agitation. When the incorporation of the ingredients has
been completely accomplished, the precipitate is settled, washed,
filtered, and dried. Following are a few recipes:--
Pale. (1) 1 cwt. barytes, 1 lb. green copperas, 1 lb. yellow
prussiate.
Pale. (2) 1 cwt. china clay, 2 lb. green copperas, 2 lb. yellow
prussiate.
Pale. (3) 1 cwt. gypsum, 1½ lb. green copperas, 1½ lb. yellow
prussiate.
Medium. (1) 1 cwt. barytes, 3 lb. green copperas, 3 lb. yellow
prussiate.
Medium. (2) 1 cwt. china clay, 6 lb. green copperas, 6 lb. yellow
prussiate.
Medium. (3) 1 cwt. gypsum, 4½ lb. green copperas, 4½ lb. yellow
prussiate.
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