Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
Carbon, lamp, and vegetable blacks consist almost entirely of carbon,
containing usually from 98 to 99½ per cent. of that substance, the
residue consisting of a little ash, water, and occasionally unburnt
oil. Bone and ivory blacks, on the other hand, are chiefly composed of
mineral matter, which may amount to 65 or 75 per cent. and is mainly
represented by phosphate of lime. Their actual colouring matter, the
carbon, only constitutes 15 to 30 per cent. of the mass. The balance is
water and unburnt animal tissue. Blacks prepared from animal matters
other than bone and ivory carry 40 to 80 per cent. of carbon, and their
mineral matter is generally in the form of carbonates of lime and of
the alkalies.
The principal impurity to be watchful of in the vegetable and lamp
blacks is a small quantity of oily matter which may seriously
interfere with their drying qualities. They should leave very
little ash after being burned in a crucible. Bone and ivory blacks
are sometimes valued as much for their mineral matter as for their
colouring matter. The proportion of this mineral matter is ascertained
by heating a certain weight of the black to red heat in a crucible till
every trace of black has disappeared, and then weighing the residue.
The residue should next be boiled in strong hydrochloric acid till
it is dissolved; if there is any which will not dissolve it is most
probably barytes, which has been added as an adulterant and to make
the black weigh heavy. When the solution is complete, the addition
of ammonia will throw down a precipitate of phosphate of lime, which
should equal 60 to 70 per cent. of the original weight of mineral
matter. If much less than this, it is likely that whiting or gypsum
has been mixed with the pigment. As carbon is not acted upon by acids
or alkalies, it follows that all pure carbon blacks are in themselves
perfectly stable and permanent pigments, and that they exert no
influence on other pigments with which they may be mixed.
=Animal-black.=--This substance is almost identical with bone-black,
but is generally in a more finely divided state. Any animal refuse
matter may be used in its preparation, such as albumen, gelatine, horn
shavings, &c. These are subjected to dry distillation in an earthenware
retort. An inflammable gas is given off, together with much oily
matter, ammonia, and water, while a black carbonaceous mass is left
behind. This is washed with water and powdered in a mill, the product
being animal-black. It is largely used in the manufacture of paint,
printing ink, and blacking.
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