Pleasant Ways in ScienceProctor, Richard A. (Richard Anthony)
Science
Pleasant Ways in Science
Proctor, Richard A. (Richard Anthony)
Science
However, the physicist must take facts as he finds them; and amongst
the most thoroughly recognized chemical facts we have this one, that
elementary substances may assume different forms. Chemists call the
phenomenon allotropy. A well-known instance of allotropy is seen in
red phosphorus. Phosphorus is one of the chemical elements; and, as
every one knows, the form in which it is usually obtained is that of a
soft, yellow, semi-transparent solid, somewhat resembling bees’ wax in
consistence, poisonous, and readily taking fire. Red phosphorus is the
same element, yet differs wholly in its properties. It is a powder, it
does not readily take fire, and it is not poisonous.
Ozone, then, is another form of oxygen. It is the only instance yet
discovered of gaseous allotropy.
And now we have to deal with the difficult and still-vexed questions
of the way in which the change from oxygen is brought about, and the
actual distinction between the two forms of the same gas. Schönbein
held that common oxygen is produced by the combination of two special
forms of oxygen—the positive and the negative, or, as he called them,
ozone and antozone. He showed that, in certain conditions of the air,
the atmospheric oxygen exhibits qualities which are the direct reverse
of those which ozone exhibits, and are distinct from those of ordinary
oxygen. In oxygen thus negatived or antozonized, animals cannot live
any more than they can in nitrogen. The products of decomposition are
not only not destroyed as by ozone, but seem subject to preservative
influences, and speedily become singularly offensive; dead animal
matter rapidly putrefies, and wounds show a tendency to mortification.
But the theory of positive and negative forms of oxygen, though still
held by a few physicists, has gradually given way before the advance
of new and sounder modes of inquiry. It has been proved, in the first
place, that ozone is denser than ordinary oxygen. The production of
ozone is always followed by a contraction of the gas’s volume, the
contraction being greater or less according to the amount of oxygen
which has been ozonized. Regularly as the observers—Messrs. Andrews
and Tait—converted a definite proportion of oxygen into ozone, the
corresponding contraction followed, and as regularly was the original
volume of the gas restored when, by the action of heat, the ozone was
reconverted into oxygen.
And now a very singular experiment was made by the observers, with
results which proved utterly perplexing to them. Mercury has the power
of absorbing ozone; and the experimenters thought that if, after
producing a definite contraction by the formation of ozone, they could
absorb the ozone by means of mercury, the quantity of oxygen which
remained would serve to show them how much ozone had been formed, and
thence, of course, they could determine the density of ozone.
Public-domain text, read in full here on John Shaqi.
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