We are dealing, as in the case of so large a part of the rocks and
minerals of the earth’s surface, with certain silicates of the alkalis
and alkaline earths, with silicates of alumina above all. All natural
clays used for fictile purposes consist essentially of silicates of
various bases, such as alumina, lime, iron, potash, and soda, more or
less intimately combined with water, and with the addition, generally,
of some free silica. If the clay be good in working quality and colour,
the next point the potter has to look to is the question of its
fusibility. It may be said generally that the simpler the constitution
of a silicate, that is the smaller the number of bases that it contains,
the greater will be its resistance to fire. Silicate of alumina is
unaltered at 1500° C., a temperature which may be taken as the maximum
at the command of the potter. The fusing-point is reduced by the
addition of silica, especially if some other bases such as oxide of iron
or lime, or again an alkali, are present even in small quantity. But
beyond a certain point the addition of silica raises the fusing-point,
and it is important to note that it is this excess of silica that
renders certain stonewares and fire-clays so infusible. In the case of
porcelain, on the other hand, the resistance to high temperatures
depends more upon the percentage of alumina present, and the absence or
small amount of other bases. Thus in comparing the composition of
different porcelains, we find that it is those that contain the most
silica that are the most fusible, or rather, to speak more accurately,
that become ‘porcelainised’ at a lower temperature.[3]
The relation of porcelain to stoneware on the one hand, and to ordinary
pottery on the other, will be made clear by the following figures, which
give the composition of stoneware, Meissen porcelain, and of a red
Samian ware:--
Stoneware. Meissen Porcelain. Samian Ware.
Silica, 80 per cent. 58 per cent. 61 per cent.
Alumina, 12 ” 36 ” 21 ”
Potash and Soda, 5 ” 5 ” 5 ”
Lime and Iron, 3 ” 1 ” 13 ”
The refractory stoneware contains a large excess of silica over the
amount required to combine with the alumina and the ‘other bases.’ In
the easily fusible Roman pottery, the ‘other bases’ nearly equal in
amount the alumina, while the Meissen porcelain not only contains less
silica than the pottery, but the ‘other bases’ only amount to a sixth
part of the alumina present.
Public-domain text, read in full here on John Shaqi.
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