But it is not enough for the manufacturer to discover a clay of which
the chemical composition corresponds to that of the type of porcelain
which he proposes to make. The question, as an experiment of Brongniart
long ago proved, is more complicated. Brongniart weighed out the
separate constituents for his porcelain--the silica, the alumina, and
the alkalis--and from them he formed his paste. He found, however, that
the paste readily melted at the heat of the porcelain furnace. The
analysis then of any ceramic product can give us but an imperfect clue
to the nature and properties of the ware. We want to know how the
elements are arranged, and this can only be inferred from a knowledge of
the materials employed in the manufacture. I will illustrate this point
by comparing the composition of Meissen porcelain with that of our
Dorsetshire pipe-clay, the most famous of our English clays, but a
material not sufficiently refractory for use in the manufacture of
porcelain. Both substances contain the same amount of alumina--36 per
cent.; in the Poole clay (after removing the water) there is 55 per
cent. of silica and 9 per cent. of ‘other bases,’ against 58 per cent.
and 6 per cent. respectively in the porcelain. The composition,
therefore, of the two bodies is nearly the same: the clay, while it
contains more iron-oxide and lime than the porcelain, is poorer in
silica.
True porcelain has indeed never been made from any other materials than
those so long employed by the Chinese and first described by the
missionary, Père D’Entrecolles, nearly two hundred years ago.
The two essential elements in the composition of porcelain are--(_a_)
The hydrated silicate of alumina, which is provided by the white earthy
clay known as kaolin or china-clay, a substance infusible at the highest
temperature attainable by our furnaces (about 1500° C.); (_b_) The
silicate of alumina and potash (or more rarely soda), that is to say
felspar. But the felspar is generally associated with some amount of
both quartz and mica, and is itself in a more or less disintegrated
condition. This is the substance known as petuntse or china-stone. It is
fusible at the higher temperatures of the porcelain kiln.
Of those substances the first is an immediate product of the weathering
of the felspar contained in granitic rocks; while the second, the
petuntse, is nothing else than the granite (or allied rock) itself in a
more or less weathered condition.
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