The principal objection to a hard refractory glaze, such as that so long
in use at Sèvres, arises from the difficulty of properly incorporating
the enamel colours with its body. The restriction of the number of
pigments that can be employed, both under and on the surface of the
glaze, in consequence of the high temperature at which the latter melts,
is another drawback. The dulness, the ‘painted on’ look of so much of
the decoration on European hard paste porcelain, is in great measure a
consequence of the employment of a glaze that is only softened at a high
temperature. As an example of a medium type of glaze we give the
composition of that used at Berlin in 1836. This consisted of kaolin, 31
per cent.; quartz, 43 per cent.; gypsum, 14 per cent.; and ground
porcelain, 12 per cent. A glaze long in use at Dresden is of a very
similar character. Felspar, it will be seen, does not enter into its
composition, and such a glaze can contain but little potash or soda.
With this we may contrast the hard glaze of Sèvres, composed simply of
ground pegmatite, a rock consisting mainly of felspar. This glaze yields
on analysis 74 per cent. of silica, 17 per cent. of alumina, and as much
as 8 per cent. of potash.
The glaze on Chinese porcelain is prepared by mixing certain special
varieties of petuntse with an impure lime, prepared by burning limestone
with dry fern as fuel. It contains, as we have seen, from 15 to 21 per
cent. of lime, 5 to 6 per cent. of alkalis, 11 per cent. of alumina, and
66 per cent. of silica.
We give these examples to illustrate the principal types of glazes used
for hard paste porcelain. It will be noticed that the constituents are
drawn from widely different sources.
The glazes of soft paste porcelain always contain a large amount both of
lead and of potash or soda, so that they approximate in composition to a
flint glass. The alkalis, generally introduced as carbonates,
necessitate a previous fritting of part at least of the materials.
Boracic acid plays an important part in the glaze of most modern English
wares: it is generally introduced in the form of borate of soda or
borax. This acid replaces in part the silica, just as in the paste the
glassy materials are replaced by bone-earth.
CHAPTER IV
DECORATION BY MEANS OF COLOUR
If we were treating the subject purely from a practical point of view,
with the glazing and firing of a piece of porcelain the manufacture
might be held to be terminated. This would be strictly true, for
instance, of the white porcelain of Berlin, so largely used in the
chemical laboratory; a great deal, too, of the china in domestic use
receives no decoration of any kind. But for us there remains still to
examine the element of colour and the way in which it is applied to the
decoration of porcelain.
Public-domain text, read in full here on John Shaqi.
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