If, then, we theoretically regard porcelain as a compound of a silicate
of alumina with an alkaline silicate of the same base, we may say that
the glaze of porcelain is formed by the latter body alone, that it is,
in fact, merely a fused felspar. But as in the case of the paste, so in
the glaze there is generally present an excess of silica, derived from
the quartz contained in the petuntse or pegmatite, and this silica
enters into combination with some other bases which are present in the
constituents of the glaze, thereby increasing its fusibility and
modifying the contraction in cooling. The most important of these
additional bases is lime, so that the more fusible type may be called a
calcareous, as opposed to a more refractory or purely felspathic glaze.
As much as 21 per cent. of lime has been found in some Chinese glazes,
the amount of alumina being proportionately reduced.
There is more or less lime in the glaze of most kinds of European hard
porcelain, but the exceptionally hard and refractory paste made at
Sèvres since the time of Brongniart is covered by a glaze of
corresponding hardness from which that earth is absent. This hard paste
has, however, of late been replaced in part by one of a milder type, and
with this latter a calcareous glaze has been adopted even at Sèvres, the
object of the change being, as we have said, to allow of a more
brilliant decoration.
There is a perceptible difference in the aspect of these two types of
glazes after firing. The hard, non-calcareous glaze has a slightly milky
look. The softer calcareous type is more brilliant, and approaches in
transparence and limpidity to the lead glazes of soft porcelain. A glaze
of this last kind was used at Sèvres for a few years after the first
introduction of the hard paste, and perhaps also at Dresden in quite
early days.
Public-domain text, read in full here on John Shaqi.
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