The protoxide of copper, especially when a certain amount of lime and
of soda is present, forms a series of beautiful blue and green
silicates. When the proportion of oxygen is decreased, as happens when
the surface of the ware is exposed in the kiln to a reducing flame, a
suboxide of copper is formed, which gives a deep and more or less opaque
red hue to the glaze. So in the case of iron, the so-called sesqui-oxide
is perhaps the most abundant source of colouring matter in the mineral
kingdom: the colours produced by it range from pale yellow to orange,
brown, and full red. When, however, the iron is present as a protoxide,
the colour given to the glaze is entirely altered; it ranges from a pale
sea-green to a deep olive.
The remaining two elements that have long played an important part in
the decoration of pottery are cobalt and manganese. These metals, in the
form of silicates, yield the well-known series of blues and purples. One
important source of the famous underglaze blue of China and Japan is a
black mineral known to us as wad, which occurs in earthy to stony
concretions. This wad contains oxides of both cobalt and manganese, and
the quality of the blue obtained from it depends in great measure upon
the proportion in which the two metals occur.
The employment of antimony is comparatively rare, but, generally in
combination with iron, it is an important source of yellow. In spite of
the volatile nature of most of its salts, in the presence of silica this
metal is able to withstand a high temperature.
But before considering the application of colour to the glaze, we must
mention briefly a method of decoration which was in great favour at
Sèvres some years ago--I mean the application of colour to the paste
itself. This was done long ago by Wedgwood, sometimes to the whole mass
of the paste, as was the case with his jasper ware, which some
authorities class as a true porcelain. At Sèvres these coloured pastes
have been generally applied to the surface only, in thin layers, or even
as mere coats of paint. When laid on in successive coats, as in the
so-called _pâte-sur-pâte_, the amount of colouring matter need not be
large, from 2 to 5 per cent. When larger proportions of coloured oxides
are mixed with the _pâte_, and this is painted on with a brush, the
process differs little from the ordinary decoration under the glaze,
into which it indeed may be said to pass. Coloured pastes of this
description have never been employed by the Chinese, and it is not
possible to obtain much brilliancy or decorative effect by their use.
They are, indeed, foreign to the nature of porcelain, sacrificing the
brilliant white ground which should be the basis of all decorative
schemes.
Public-domain text, read in full here on John Shaqi.
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