When the colouring matter is subjacent to the glaze it must be of a
nature to withstand the full heat of the subsequent firing; we are
restricted therefore to colours ‘_à grand feu_.’ This practically
confines us to cobalt and to certain combinations of iron and copper, as
far as the ‘old palette’ is concerned. At Sèvres and elsewhere other
metals have been made use of whose silicates withstand the extreme
temperature of the kiln. By the use of chromium we have command of many
shades of green. If to an oxide of tin we add a minute quantity of the
sesqui-oxide of chromium, we can obtain, in the presence of lime, many
shades from rose to purple; and a mixture of cobalt and chromium
produces a fine black. There is, however, as yet no satisfactory yellow
pigment known that will withstand the _grand feu_. At the best we can
get a straw colour from certain ores of tungsten and titanium, and from
uranium a yellow deeper in tint but uncertain in application.
The majority of the colours we have mentioned require a more or less
oxidising flame for their full development. There are, however, two most
important groups of coloured glazes, long the monopoly of the Chinese,
but now successfully imitated in France and elsewhere, which require,
for a term at least, to be subjected to a reducing flame.
The first of these glazes is the well-known CELADON, using that term in
its proper and restricted sense, for certain shades of greyish green.
The celadon of the Chinese is produced by the presence of a small
quantity, about two per cent., of protoxide of iron in the glaze. An
oxidising flame would change this protoxide to the yellow sesqui-oxide.
We may note that a celadon of good tint can only be produced when a
considerable quantity of lime is present in the glaze.
The other group, depending also upon a reducing flame, is constituted by
the famous SANG DE BŒUF and FLAMBÉ glazes.
Public-domain text, read in full here on John Shaqi.
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