The colour of the first is given by the red sub-oxide of copper, chiefly
suspended in the glaze. In the case of the _flambé_ or ‘transmutation’
glazes, the strange caprices of colour have their origin, in part at
least, in the contrast of the red sub-oxide and the green silicate of
copper. In the case of both these glazes everything depends on the
regulation of the draught of the furnace in which they are fired. The
French have lately been at great pains to master the difficulties
attendant upon the development of the effects sought after, and some
success has been attained not only on a porcelain ground as at Sèvres,
but these glazes have also been applied to fayence at the Golfe St. Juan
and elsewhere. It has been proved by some experiments made at Sèvres,
that in the firing, the critical period, during which so much depends
upon the regulation of the draught, is _just before_ the melting of the
glaze. Once melted the glaze not only forms an impervious cover which
prevents the smoky flame from discolouring the paste below, but the
glaze itself is no longer sensitive to the action of the gases which
surround it. It is therefore only during a short period preceding the
moment when the glaze begins to melt, that it is necessary to promote a
smoky and reducing flame. This is a point of considerable practical
importance.[20]
The application of the DECORATION UNDER THE GLAZE is essentially a
Chinese method. To it we owe the important family of ‘blue and white’
ware. The superiority of the Chinese in the management of the blue
colour has been attributed to various causes. The result is no doubt
influenced not only by the constitution of both paste and glaze, but
also by the fact that the colour is painted upon the _raw_ paste.
An important factor also is the care exercised by the Chinese in the
selection and preparation of the blue pigment, by which not only the
desired intensity but the richness of hue is secured. The quality of the
blue depends in great measure upon the presence of a small quantity of
manganese in the cobalt ore employed.
The only other colour that the Chinese have succeeded in using under the
glaze is the red derived from the sub-oxide of copper. The full
development of this colour has for long been a lost art, but a less
brilliant red from this source, often little better than a buff colour,
is sometimes found in later examples combined with the blue.
In the application of colours under the glaze there is one difficulty
that the Chinese have surmounted even in their commonest ware, and this
is the tendency of the cobalt blue to dissolve and ‘run’ in the glaze,
giving to the design a blurred and indistinct appearance. It would seem
that the sharpness of outline depends upon the consistency of the glaze
at the moment when it first melts. At that point the glaze should be
viscous and not inclined to flow, and this is what occurs in the case
of the highly calcareous glazes of the Chinese.
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