The colouring matter in the European enamels may amount to as much as a
third part of the total amount of the flux with which they are
incorporated. As there is not enough of this flux to dissolve the whole
of the oxides, the enamel remains dull and opaque after firing. The
flux, in fact, is only used as a vehicle to attach the colour to the
surface of the porcelain. The effect in consequence is inferior in
brilliancy to that obtained by the Chinese with their transparent
enamels in which the metallic oxides, present in much smaller quantity,
are thoroughly dissolved to form a glass. There is, unfortunately, a
practical obstacle to the application of these glassy enamels to the
hard pastes and glazes of Europe. It is impossible to ensure their firm
adhesion to the subjacent glaze. The Chinese, however, do not appear to
find any difficulty in effecting this. The following explanation has
been given to account for the difference of behaviour:--the tendency of
the enamel to split off in cooling, as has been proved by experiment,
arises from the small amount of contraction at that time of the highly
kaolinic paste, compared with that of the superimposed glassy enamel.
The more silicious paste used by the Chinese contracts, on the contrary,
at the same rate approximately as the enamels that it carries, and
these enamels may therefore be laid on in sufficient thickness without
any risk of their subsequently splitting off.[22] To appreciate the
difference in the decorative value of these two classes of enamels it is
only necessary to compare the brilliant effect, say, of a piece of
Chinese egg-shell of the time of Kien-lung with the tame surface of a
contemporary Meissen plate, elaborately painted with landscapes or
flowers.
The glassy enamels used by the Chinese resemble the pastes used for
artificial jewellery. They are essentially silicates of lead and an
alkali. The composition of the flux has to be modified to ensure the
full development of the colour of the different metallic oxides which
are either made up with it or added subsequently. But in a general way
we may say that the colourless fluxes which form the basis of the
coloured enamels are prepared by melting in a crucible a mixture of pure
quartz sand and red lead, and adding more or less alkali. In certain
cases the lead predominates, as when it is proposed to make an emerald
green enamel by means of copper, or when the flux is to serve as a basis
for the ruby colour given by a minute quantity of gold. On the other
hand, if copper be added to a flux containing an excess of either soda
or potash, we obtain a turquoise blue. A fine purple, again, can only be
obtained from manganese with an alkaline flux; if too much lead is
present only a brown tint is obtainable.
Public-domain text, read in full here on John Shaqi.
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