To melt these enamels and to ensure their adherence to the subjacent
glaze another firing at a gentler temperature is necessary; indeed in
many cases more than one such firing has to be resorted to. The
comparatively high temperature required to develop the colour of one
enamel may be sufficient to decompose or otherwise damage another part
of the decoration. The lowest temperature of all is that of the
muffle-fire in which the gilding is fixed. This is therefore the last
decoration to be added.
The oven in which these enamels are melted on to the surface of the
already glazed porcelain is called a muffle. The ware in this case is
protected from the direct action of the flame by the closed rectangular
box of fireclay in which it is placed, like bread in a baker’s oven. The
muffle is placed over the fireplace of a rectangular furnace, and the
flame plays round the sides in such a way as to ensure the uniform
distribution of the heat. For the sake of greater cleanliness and the
avoidance of dust, the pieces to be fired are placed upon tiles of
porcelain rather than upon biscuit or fireclay supports. The temperature
may vary from a dull to a full red heat (600° to 1000°C.), and the
firing lasts from four to twelve hours.
We have already mentioned incidentally many of the so-called
‘muffle-colours’ or enamels. Those used in China were carefully studied
some years ago by Ebelmen and Salvétat at Sèvres. It would appear that
the opaque white of the Chinese is obtained from arsenic--the merits of
the use of tin for this purpose appear to be unknown to them. The blacks
are made from the already mentioned cobalt-manganese ore (wad), mixed
with white lead--when oxide of copper is added a more lustrous black is
obtained.[23] For the blue enamel, a very small quantity of cobalt
suffices to give a brilliant colour. The various tints of the greens and
blues derived from copper depend on the nature of the flux; of this we
have already given an instance. Antimony in combination with lead gives
a bright yellow, which tends to orange when a little iron is present; by
the addition of more iron the colour of old bronze is imitated. Iron in
the state of the sesqui-oxide is the source of many shades of red, but
as this iron oxide will not readily combine with silica to form a
transparent glass, it has to be applied as a more or less opaque paint,
and thus differs from the other colours in being in perceptible relief.
Hence the importance of the ruby red derived from gold, which was first
introduced into China in the early part of the eighteenth century, and
soon became the predominating colour in the decoration of the time (the
_famille rose_).
Public-domain text, read in full here on John Shaqi.
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