Practical Hand Book of Gas, Oil and Steam Engines: Stationary, Marine, Traction; Gas Burners, Oil Burners, Etc.; Farm, Traction, Automobile, Locomotive; A simple, practical and comprehensive book on the construction, operation and repair of all kinds of engines. Dealing with the various parts in detail and the various types of engines and also the use of different kinds of fuel.Rathbun, John B.
Science
Practical Hand Book of Gas, Oil and Steam Engines: Stationary, Marine, Traction; Gas Burners, Oil Burners, Etc.; Farm, Traction, Automobile, Locomotive; A simple, practical and comprehensive book on the construction, operation and repair of all kinds of engines. Dealing with the various parts in detail and the various types of engines and also the use of different kinds of fuel.
Rathbun, John B.
Internal combustion engines; Traction-engines
Current is produced in a primary battery by the chemical action of a
fluid known as an =ELECTROLYTE= upon two dissimilar metals or solids
known as the electrodes. One of the electrodes, the negative, is usually
made of zinc which is more readily attacked by the electrolyte than the
positive electrode. As the metal of the negative electrode is dissolved
and passes into the solution during the process of current generation,
the electrolyte is also exhausted. The production of current is
accompanied by the liberation of hydrogen gas from the electrolyte from
which it is displaced by the zinc taken into solution.
When the electrodes are immersed in the electrolyte, and the outer ends
of the electrodes are connected with a wire, a current will flow from
the positive electrode to the negative through the wire, and from the
negative to the positive electrode through the fluid. It will be seen
that to complete the circuit between the electrodes it is necessary that
the current flows through the electrolyte.
Electrical energy is actually generated in the primary battery by the
chemical combustion of the negative electrode in the same way that heat
energy is developed by the burning of a fuel.
By connecting the binding posts of the electrodes to the two wires of
the external circuit, a current will flow through the circuit as long as
the electrodes remain undissolved, or until the positive electrode is
covered with hydrogen gas bubbles.
The bubbles of gas tend to insulate the positive electrode from the
electrolyte or fluid, thus breaking the circuit through the fluid, and
stopping the flow of current. This action is known as polarization.
When a battery is polarized, the only remedy is to disconnect it from
the circuit and allow it to rest or recuperate. The greater the current
drawn from a battery, the more rapid the polarization, and it is evident
that if the battery is to be used for long periods, polarization must be
eliminated, or the current must be considerably reduced in volume. A
battery that delivers a small current has a much greater capacity in
ampere hours than a battery that has a higher rate of discharge. The
greater the discharge rate the longer must be the rest periods.
A battery that is designed for continuous service, or for delivering
heavy currents of long duration, is called a closed-circuit battery.
Polarization is eliminated in closed circuit batteries by various
methods, the usual methods being to place some substance in the
electrolyte that will destroy the hydrogen film; or by packing some
solid oxidizing material around the positive electrode that will absorb
the hydrogen; or by making the positive electrode of some material that
will destroy the hydrogen as soon as it is developed.
Public-domain text, read in full here on John Shaqi.
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