=7. Carbon= as an elementary substance occurs as diamond and graphite and in an impure form as anthracite and bituminous coals. In peats and mucks carbon is the chief constituent. This substance is also contained in the organic matters of the soil known as humus, and the relation of the carbon to nitrogen often throws important light upon the amount and character of the nitrogenous matters. In composition with oxygen it forms the chief food of growing plants, the carbon of the carbon dioxid of the air being elaborated into the tissue of the plants and the oxygen returned to the atmosphere. The content of carbon dioxid in the air is from three to five parts per thousand by volume. As carbonates this element helps to form some of the most important ingredients of the earth’s crust, namely, limestones, marbles, dolomites, etc., and in an organic form it is found in the shells of the crustaceans. The calcareous matter of the soil, that is, the carbonates of the earths therein found, are of the highest importance from an agricultural point of view. The carbonates in the soil not only favor the process of converting nitrogenous bodies into forms suitable for plant food, but also exert a most potent influence on the physical state of the soil and its capacity for holding water and permitting its flow to and from the rootlets of the plant. =8. Sulfur= occurs in nature in both the free and combined state. In the free state it is found in volcanic regions such as Sicily, Iceland, and the western United States. Its usual form of occurrence is in combination with the metals to form sulfids, or with oxygen and a metal to form sulfates. Sulfur and iron combine to form iron pyrites or iron disulfid (FeS₂), while sulfur, oxygen, and calcium are found in gypsum, an important fertilizing compound. Sulfur plays an important part in the nourishment of plants, being found in them both as sulfuric acid and in organic compounds. Methods for estimating the sulfur in both forms will be found in another part of this manual. =9. Hydrogen= is a colorless, invisible gas, without taste or smell. It occurs free in small proportions in certain volcanic gases, and in natural gas, but its most common form is in combination with oxygen as water (H₂O), of which it forms 11.13 per cent by weight. It also occurs in combination with carbon to form the hydrocarbons, such as the mineral oils (petroleum, etc.) and gases. Hydrogen is of no importance to agriculture in a free state, but water is the most important of all plant foods.