=10. Chlorin= occurs free in nature only in limited amounts and in
volcanic vents. Its most common form is in combination with hydrogen,
forming hydrochloric acid, or with the metals to form chlorids. It
combines with sodium to form sodium chlorid or common salt (NaCl), which
is the most abundant mineral ingredient in sea water and which can
usually be detected in rain and ordinary terrestrial waters. In this
form, also, it exists as extensive beds of rock salt, which is mined for
commercial purposes.
Chlorin is found uniformly in plants and must be regarded as an
essential constituent thereof. Common salt applied to a soil modifies
its power of attracting and holding water.
=11. Phosphorus= never occurs in nature in a free state but exists in
combination in greater or less quantities in all soils. Its combinations
are also found in large deposits of minerals known as phosphorite and
apatite and as so-called pebble deposit and phosphate rock. Phosphorus
in some sort of combination is one of the most essential elements in
animal and plant food. In animals its compounds form almost all of the
mineral matter of the bones, and in plants they are the chief
constituents of the ash of seeds.
The mineral deposits of phosphorus, as well as bones, are chiefly
tri-calcium phosphate, while the slag compound resulting from the basic
treatment of iron ores rich in phosphorus is a tetra-calcium salt.
The pebble deposits and some rock phosphates are supposed to be of
organic origin, derived from the remains of marine, terrestrial, and
aerial animals.
Cereal crops remove about twenty pounds of phosphoric acid per acre from
the soil annually and grass crops about twelve pounds. The total
phosphoric acid removed annually by the cereal and grass crops in the
United States is nearly four billion pounds.
Gautier[1] calls attention to the fact that the oldest phosphates are
met with in the igneous rocks such as basalt, trachyte, etc., and even
in granite and gneiss. It is from these inorganic sources, therefore,
that all phosphatic plant food must have been drawn. In the second order
in age Gautier places the phosphates of hydro-mineral origin. This class
not only embraces the crystalline apatites but also those phosphates of
later formation formed from hot mineral waters in the jurassic,
cretaceous, and tertiary deposits. These deposits are not directly
suited to nourish plants.
The third group of phosphates in order of age and assimilability
embraces the true phosphorites containing generally some organic matter.
They are all of organic origin. In caves where animal remains are
deposited there is an accumulation of nitrates and phosphates.
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