Not only do the bones of animals furnish phosphates but they are also
formed in considerable quantities by the decomposition of substituted
glycerids such as lecithin. The ammonia produced by the nitrification of
the albuminoid bodies combines with the free phosphoric acid thus
produced, forming ammonium or diammonium phosphates. The presence of
ammonium phosphates in guanos was first noticed by Chevreul more than
half a century ago.
If such deposits overlay a pervious stratum of calcium carbonate, such
as chalk, and are subject to leaching a double decomposition takes place
as the lye percolates through the chalk. Acid calcium phosphate and
ammonium carbonate are produced. By further nitrification the latter
becomes finally converted into calcium nitrate. In like manner aluminum
phosphates are formed by the action of decomposing organic matter on
clay.
Davidson,[2] explains the origin of the Florida phosphates by suggesting
that they arose chiefly through the influx of animals driven southward
during the glacial period. According to his supposition the waters of
the ocean, during the cenozoic period contained more phosphorus than at
the present time. The waters of the ocean over Florida were shallow and
the shell fish existing therein may have secreted phosphate as well as
carbonate of lime. This supposition is supported by an analysis of a
shell of _lingula ovalis_, quoted by Dana, in which there were 85.79 per
cent of lime phosphate. In these waters were also many fishes of all
kinds and their débris served to increase the amount of phosphatic
material. As the land emerged from the sea came the great glacial epoch
driving all terrestrial animals southward. There was, therefore, a great
mammal horde in the swamps and estuaries of Florida. The bones of these
animals contributed largely to the phosphatic deposits. In addition to
this, the shallow sea contained innumerable sharks, manatees, whales,
and other inhabitants of tropical waters, and the remains of these
animals added to the phosphatic store.
While these changes were taking place in the quaternary period, the
Florida Peninsula was gradually rising, and as soon as it reached a
considerable height the process of denudation by the action of water
commenced. Then there was a subsidence and the peninsula again passed
under the sea and was covered with successive layers of sand. The
limestones during this process had been leached by rain water containing
an excess of carbon dioxid. In this way the limestones were gradually
dissolved while the insoluble phosphate of lime was left in suspension.
During this time the bones of the animals before mentioned by their
decomposition added to the phosphate of lime present in the underlying
strata, while some were transformed into fossils of phosphate of lime
just as they are found to-day in vast quantities.
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