According to Dr. N. A. Pratt the rock or bowlder phosphate had its
immediate origin in animal life and to his view the phosphate bowlder is
a true fossil. He supposes the existence of some species in former times
in which the shell excreted was chiefly phosphate of lime. The fossil
bowlder, therefore, becomes the remains of a huge foraminifer which had
identical composition in its skeleton with true bone deposits or of
organic matter.
Perhaps the most complete exposition of the theory of the recovery of
waste phosphates, with especial reference to their deposit in Florida,
has been given by Eldridge.[5] He calls attention to the universal
presence of phosphates in sea water and to the probability that in
earlier times, as during the miocene and eocene geologic periods, the
waters of the ocean contained a great deal more phosphate in solution
than at the present time. He cites the observations of Bischof, which
show the solubility of different phosphates in waters saturated with
carbon dioxid. According to these observations apatite is the most
insoluble form of lime phosphate, while artificial basic phosphate is
the most soluble. Among the very soluble phosphates, however, are the
bones of animals, both fresh and old. Burnt bones, however, are more
soluble than bones still containing organic matter. Not only are the
organic phosphates extremely soluble in water saturated with carbon
dioxid, but also in water which contains common salt or chlorid of
ammonium. The presence of large quantities of common salt in sea water
would, therefore, tend to increase its power of absorbing lime
phosphates of organic origin. It is not at all incredible, therefore, to
suppose that at some remote period the waters of the ocean, as indicated
by these theories, were much more highly charged with phosphates in
solution than at the present time.
According to Eldridge, the formation of the hard-rock and soft
phosphates may be ascribed to three periods: First, that in which the
primary rock was formed; second, that of secondary deposition in the
cavities of the primary rock; third, that in which the deposits thus
formed were broken up and the resulting fragments and comminuted
material were redeposited as they now occur.
Public-domain text, read in full here on John Shaqi.
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