“The first of these stages began probably not later than the close of
the older miocene, and within the eocene area it may have begun much
earlier. Whether the primary phosphate resulted from a superficial and
heavy deposit of soluble guanos, covering the limestones, or from the
concentration of phosphate of lime already widely and uniformly
distributed throughout the mass of the original rock, or from both, is a
difficult question. In any event, the evidence indicates the effect of
the percolation of surface waters, highly charged with carbonic and
earth acids, and thus enabled to carry down into the mass of the
limestone dissolved phosphate of lime, to be redeposited under
conditions favorable to its separation. Such conditions might have been
brought about by the simple interchange of bases between the phosphate
and carbonate of lime thus brought together, or by the lowering of the
solvent power of the waters through loss of carbonic acid. The latter
would happen whenever the acid was required for the solution of
additional carbonate of lime, or when, through aeration, it should
escape from the water. The zone of phosphate deposition was evidently
one of double concentration, resulting from the removal of the soluble
carbonate thus raising the percentage of the less soluble phosphate, and
from the acquirement of additional phosphate of lime from the overlying
portions of the deposits.”
“The thickness of the zone of phosphatization in the eocene area is
unknown, but it is doubtful if it was over twenty feet. In the miocene
area the depth has been proved from the phosphates _in situ_ to have
been between six and twelve feet.”
The deposits of secondary origin, according to Eldridge, are due chiefly
to sedimentation, although some of them may have been due to
precipitation from water. This secondary deposition was kept up for a
long period, until stopped by some climatic or geologic change. The
deposits of phosphates thus formed in the Florida peninsula are
remarkably free from iron and aluminum, in comparison with many of the
phosphates of the West Indies.
The third period in the genesis of the hard rock deposits embraces the
time of formation of the original deposits and their transportation and
storage as they are found at the present time. The geologic time at
which this occurred is somewhat uncertain but it was probably during the
last submergence of the peninsula.
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