Immense quantities of waste nitrogen are further secured, both from sea
and land, by the various genera of birds. The well-known habit of birds
in congregating in rookeries during the night and at certain seasons of
the year tends to bring into a common receptacle the nitrogenous matters
which they have gathered and which are deposited in their excrement and
in the decay of their bodies. The feathers of birds are particularly
rich in nitrogen, and the nitrogenous content of the flesh of fowls is
also high. The decay of remains of birds, especially if it take place
largely excluded from the leaching of water, tends to accumulate vast
deposits of nitrogenous matter. If the conditions in such deposits be
favorable to the processes of nitrification, the whole of the nitrogen,
or at least the larger part of it, which has been collected in this
débris, becomes finally converted into nitric acid and is found combined
with appropriate bases as deposits of nitrates. The nitrates of the
guano deposits and of the deposits in caves arise in this way. If these
deposits be subject to moderate leaching the nitrate may become
infiltered into the surrounding soil, making it very rich in this form
of nitrogen. The bottoms and surrounding soils of caves are often found
highly impregnated with nitrates.
While for our purpose, deposits of nitrates only are to be considered
which are of sufficient value to bear transportation, yet much interest
attaches to the formation of nitrates in the soil even when they are not
of commercial importance.
In many of the soils of tropical regions not subject to heavy
rain-falls, the accumulation of these nitrates is very great. Müntz and
Marcano[12] have investigated many of these soils to which attention was
called first by Humboldt and Boussingault. They state that these soils
are incomparably more rich in nitrates than the most fertile soils of
Europe. The samples which they examined were collected from different
parts of Venezuela and from the valleys of the Orinoco as well as on the
shore of the Sea of Antilles. The nitrated soils are very abundant in
this region of South America where they cover large surfaces. Their
composition is variable, but in all of them carbonate and phosphate of
lime are met with and organic nitrogenous material. The nitric acid is
found always combined with lime. In some of the soils as high as thirty
per cent of nitrate of lime have been found. Nitrification of organic
material takes place very rapidly the year round in this tropical
region. These nitrated soils are everywhere abundant around caves, as
described by Humboldt, caves which serve as the refuge of birds and
bats. The nitrogenous matters, which come from the decay of the remains
of these animals, form true deposits of guano which is gradually spread
around, and which, in contact with the limestone and with access of air,
suffers complete nitrification with the fixation of the nitric acid by
the lime.
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