Large quantities of this guano are also due to the débris of insects, fragments of elytra, scales of the wings of butterflies, etc., which are brought together in those places by the millions of cubic meters. The nitrification, which takes place in these deposits, has been found to extend its products to a distance of several kilometers through the soil. In some places the quantity of the nitrate of lime is so great in the soils that they are converted into a plastic paste by this deliquescent salt. The theory of Müntz and Marcano in regard to the nitrates of soils, especially in the neighborhood of caves, is probably a correct one, but there are many objections to accepting it to explain the great deposits of nitrate of soda which occur in many parts of Chile. Another point, which must be considered also, is this: That the processes of nitrification can not now be considered as going on with the same vigor as formerly. Some moisture is necessary to nitrification, inasmuch as the nitrifying ferment does not act in perfectly dry soil, and in many localities in Chile where the nitrates are found it is too dry to suppose that any active nitrification could now take place. The existence of these nitrate deposits has long been known.[13] The old Indian laws originally prohibited the collection of the salt, but nevertheless it was secretly collected and sold. Up to the year 1821, soda saltpeter was not known in Europe except as a laboratory product. About this time the naturalist, Mariano de Rivero, found on the Pacific coast, in the Province of Tarapacá, immense new deposits of the salt. Later the salt was found in equal abundance in the Territory of Antofogasta and further to the south in the desert of Atacama, which forms the Department of Taltal. At the present time the collection and export of saltpeter from Chile is a business of great importance. The largest export which has ever taken place in one year was in 1890, when the amount exported was 927,290,430 kilograms; of this quantity 642,506,985 kilograms were sent to England and 86,124,870 kilograms to the United States. Since that time the imports of this salt into the United States have largely increased. According to Pissis[14] these deposits are of very ancient origin. This geologist is of the opinion that the nitrate deposits are the result of the decomposition of feldspathic rocks; the bases thus produced gradually becoming united with the nitric acid provided from the air.