For the purpose of drying materials contained in flasks and tubes
in a current of hydrogen the apparatus shown in Fig. 11 is used.
This apparatus consists of a circular box, B, conveniently made of
galvanized iron, having a movable cover, S, fitted for the introduction
of steam into the interior of the apparatus. Condensed steam escapes at
W. A stream of perfectly pure and dry hydrogen enters at H, passes up
through the material to be dried, down through the bulb V, containing
sulfuric acid, and follows the direction of the arrows through the rest
of the apparatus. The stream of hydrogen is thus completely dried by
passing through bulbs containing sulfuric acid, on the way from one
piece of the apparatus to the other. A, represents a flask such as is
used, with the extraction apparatus described. The apparatus which we
have used will hold eight tubes or flasks at a time, and thus a single
stream of hydrogen is made to do duty eight times in drying eight
separate samples. The great advantage of the apparatus is in the fact
that the stream of hydrogen must pass over and through the substance
to be dried. In order to prevent any sulfuric acid from being carried
forward into the next tube the bulb K, above the sulfuric acid, may be
filled with solid pieces of soda or potash.
This apparatus has been in use for a long time and no accidents from
sulfuric acid being carried forward have occurred, and there is no
danger, provided the stream of hydrogen is kept running at a slow
rate. If, however, by any accident the stream of hydrogen should be
admitted with great rapidity, particles of the sulfuric acid might be
carried forward and spoil the next sample. To avoid any such accident
as this the proposal to introduce the potash bulb has been made. The
apparatus works with perfect satisfaction, and it is believed that when
properly adjusted check weighings can be made by weighing the bulbs,
showing their increase in weight, which will give the volatile matter,
and weighing the flasks or tubes, which will show the loss of weight.
The only chance for error in weighing the bulbs is that some of the
volatile matter may be material which is not dissolved in sulfuric
acid, and is thus carried on and out of the apparatus. The blackening
of the sulfuric acid in the bulbs, in the drying of all forms of
organic matter, shows that the loss in weight of such bodies is not
due to water alone, but also to organic volatile substances, which are
capable of being decomposed by the sulfuric acid, thus blackening it.
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