Drying in partial vacuum and in a slowly changing atmosphere may
be practiced with all bodies and must be employed with some. The
simple form of apparatus already described will be found useful for
this purpose. At a vacuum of twenty inches or more, even unstable
organic agricultural products are in little danger of oxidation. In
the introduction of a dry gas, therefore, air will be found as a
rule entirely satisfactory. In the smaller form of vacuum apparatus
described, however, there is no objection to the employment of hydrogen
or of carbon dioxid. The gas entering the apparatus should be dried
by passing over calcium chlorid or by bubbling through sulfuric acid.
In this laboratory the vacuum is provided by an air-pump connected
with a large exhaust cylinder. This cylinder is connected by a system
of pipes to all the working desks. The chief objection to this system
is the unsteadiness of the pressure. When only a few are using the
vacuum apparatus for filtering or other purposes the vacuum will stand
at about twenty inches. When no one is using it the vacuum will rise
to twenty-eight or twenty-nine inches. At other times, when in general
use, it may fall to fifteen inches. Where a constant vacuum is desired
for drying, therefore, it is advisable to connect the apparatus with a
special aspirator which will give a pressure practically constant.
The dishes containing the sample should be low and flat, exposing as
large a surface as possible. For viscous liquids it will be found
advisable to previously fill the dishes with pumice stone or other
inert absorbent material to increase the surface exposed.
The special methods of drying milk, sirup, honeys, and like bodies,
will be described in the paragraphs devoted to these substances.
In drying agricultural products, not only water but all other matters
volatile at the temperature employed are expelled. It is only necessary
to conduct the products of volatilization through sulfuric acid to
demonstrate the fact that organic bodies are given off. In the case
mentioned the sulfuric acid will be speedily changed to a brown and
even black color by these bodies. It is incontestable, however, that
in most cases the essential oils and other volatile matters thus
escaping are not large in quantity and could not appreciably affect
the percentage composition of the sample. In such cases the whole of
the loss on drying is entered in the note book as water. There are
evidently many products, however, where a considerable percentage of
the volatile products is not water. The percentage of essential oils,
which have a lower boiling-point than water, can be determined in a
separate sample and this deducted from the total loss on drying will
give the water.
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