A more detailed description of the different parts of the apparatus
can be seen by consulting Figs. 19, 20, and 21. In A, Fig. 19, is
represented a section of the flask which holds the solvent, showing
how the sides of the hood containing the matters to be extracted pass
over the neck of the flask, and showing at S a small siphon inserted
in the space between the neck of the flask and the walls of the hood
for the purpose of removing any solvent that may accumulate in this
space. A view of the flask itself is shown at Aʹ. It is made by taking
an ordinary flask, softening it about the neck and pressing the neck
in so as to form a cup, as indicated at Aʹ, to hold the mercury which
seals the union of the flask with the condenser. The flask is held in
position by passing a rubber band below it, which is attached to two
glass nipples, _b_, blown onto the containing vessel, as shown in Fig.
18. The material to be extracted may be contained in an ordinary tube,
as shown in Fig. 20, which may be made from a test tube drawn out, as
indicated in the figure, having a perforated platinum disk sealed in
at D. The containing tube rests upon the edges of the flask containing
the solvent by means of nipples shown at _t_. If a siphon tube is to
be used, one of the most convenient forms is shown in Fig. 21, in
which the siphon lies entirely within the extracting tube, thus being
protected from breakage. By means of this apparatus the extractions
can be carried on with a very small quantity of solvent, there being
scarcely any leakage, even with the most volatile solvents, such as
ether and petroleum. The apparatus is always ready for use, no corks
are to be extracted, and no ground glass joints to be fitted.
=40. Soxhlet’s Extraction Apparatus.=—A form of continuous extraction
apparatus has been proposed by Soxhlet which permits the passage of
the vapors of the solvent into the condenser by a separate tube and
the return of the condensed solvent after having stood in contact
with the sample, to the evaporating flask by a siphon. The advantage
of this process lies in freeing the sample entirely from the rise of
temperature due to contact with the vapors of the solvent, and in the
second place in the complete saturation of the sample with the solvent
before siphoning. The sample is conveniently held in a cylinder of
extracted filter-paper open above and closed below. This is placed
in the large tube between the evaporating flask and the condenser.
The sample should not fill the paper holder, and if disposed to float
in the solvent, should be held down with a plug of asbestos fiber
or of glass wool. The extract may be transferred, by dissolving in
the solvent, from the flask to a drying dish, or it may be dried and
weighed in the flask where first received.
[Illustration: FIGURE 22. SOXHLET EXTRACTION APPARATUS.]
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