Principles and Practice of Fur Dressing and Fur DyeingAustin, William E.
Science
Principles and Practice of Fur Dressing and Fur Dyeing
Austin, William E.
Fur -- Dressing and dyeing
When the skins are mordanted before dyeing, they are immersed for 6 to
24 hours in a solution containing 1 to 20 grams of the metallic salts per
liter of water, together with the corresponding quantity of the assistant
chemical. The skins should be so entered into the mordant solution that
the hair is uniformly in contact with the solution, and all the skins
so that they are acted upon alike. Machinery such as is used for killing
is suitable for mordanting also. The duration of the mordanting, and the
concentration of the solutions are varied according to the depth of shade
required, and also according to the nature of the dye to be employed. By
suitably combining several mordants a considerable range of colors can be
obtained with a single dye.
The various chemicals used as mordants are essentially the same no matter
for which class of dyes they are used, there being only slight differences
in the concentrations of the solutions, the manner of application of
the mordants being practically the same. It is interesting to note that
with the exception of chromium compounds, which are of comparatively
recent adoption as mordants, all the chemicals now used for mordants
were employed by the earliest masters of the art of fur dyeing. While
some of the formulas used by those dyers display a lack of appreciation
of the true action and function of the mordanting chemicals, yet it is
quite remarkable that they chose, in spite of their limited knowledge of
chemical processes and phenomena, just those materials which do act as
mordants if properly applied. The most important metallic compounds for
mordanting furs at the present time are salts of aluminum, iron (ferrous),
copper, tin and chromium (as well as chromates and bichromates). The
compounds of the metals with organic acids such as acetic acid are
preferable, being more easily dissociated, and also leaving in solution
an acid which is less injurious to the fur than a mineral acid. However,
sulphates and other salts of the metals are also used extensively,
inasmuch as they are cheaper than the organic salts.
ALUMINUM MORDANTS
Chief among the aluminum mordants are the various kinds of alum, which is
a double sulphate of aluminum and an alkali such as sodium, potassium or
ammonium. All these salts except that of sodium, form large, colorless,
octahedral crystals, and are soluble in about 10 parts of cold water,
and 1/4 part of hot water. Sodium alum is even more easily soluble, but
on account of the difficulty of obtaining it in crystalline form, it
is little used. The common commercial alum is the potassium aluminum
sulphate.
Recently, aluminum sulphate has to a large extent replaced alum for
mordanting purposes, because it can be obtained very cheaply in pure form,
and it contains a greater amount of active aluminum compound than does
alum. Only the iron-free salt, however, may be used for the needs of fur
dyeing.
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