Principles and Practice of Fur Dressing and Fur DyeingAustin, William E.
Science
Principles and Practice of Fur Dressing and Fur Dyeing
Austin, William E.
Fur -- Dressing and dyeing
Aluminum acetate also finds extensive application as a mordant in fur
dyeing, and while somewhat more expensive than the alum or aluminum
sulphate, it has the advantage over these compounds of being combined
with an organic acid, which is preferable when the action on the hair and
leather is considered. Aluminum acetate can be obtained in the market in
the form of a solution of 10 degrees Beaumé, but can also be prepared very
easily as follows:
665 grams pure aluminum sulphate, or
948 grams potassium alum, are dissolved in
1 liter of hot water.
1137 grams of lead acetate (sugar of lead) are also dissolved in
1 liter of hot water.
The two solutions are mixed, and thoroughly stirred. A heavy white
precipitate forms, which is filtered off, and discarded after the solution
has cooled. The aluminum acetate is contained in the filtrate, and the
solution is brought to a density of 10 degrees Beaumé by the addition of
water, if necessary, and is preserved for use in this form.
IRON MORDANTS
Ferrous sulphate, iron vitriol, or copperas, as it is commonly known,
forms pale green crystals, which on exposure to air lose water, and
crumble down to a white powder. It is very soluble in both cold and
hot water, but the solutions oxidize very rapidly, turning yellowish,
and should therefore be used immediately. Care must be taken that a
good quality of iron vitriol be used for the mordant, otherwise very
unsatisfactory results will be obtained.
Ferrous acetate is prepared in a manner similar to the aluminum acetate,
and is occasionally employed instead of the ferrous sulphate. Inasmuch,
however, as the solution of ferrous acetate is very easily oxidizable
when exposed to the air, a more stable form is used, and this comes on
the market as iron pyrolignite or iron liquor. This can be prepared by
dissolving iron in crude acetic or pyroligneous acid, or by treating a
solution of iron sulphate with calcium pyrolignite. Iron liquor is really
a solution of ferrous acetate that contains certain organic impurities
which prevent, or rather, considerably retard the oxidation of the iron
salt, but which in no way interfere with its mordanting properties. The
commercial product can be had in various concentrations, but 10 degrees
Beaumé is the most usual and most convenient.
COPPER MORDANTS
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