Pyrometry: A Practical Treatise on the Measurement of High TemperaturesDarling, Charles R. (Charles Robert)
Science
Pyrometry: A Practical Treatise on the Measurement of High Temperatures
Darling, Charles R. (Charles Robert)
Pyrometry
The hot junction is allowed to attain these temperatures successively,
and the corresponding deflection in each case is noted. It is then
possible to divide up the whole of the scale to read temperatures
directly.
The first reading is taken by placing the junction in a vessel of
boiling water, and for a locality near sea level it is not necessary
in ordinary work to take account of fluctuations in the boiling point
due to alterations of atmospheric pressure. To ensure that the other
readings are taken when the substances are exactly at the melting
point, the procedure is as follows: about 2-3 lb. of the substance are
melted in a salamander crucible, and a small fireclay tube, closed at
one end, is inserted in the molten mass. The hot junction is placed
in the fireclay tube, and the intervening space filled with asbestos
fibre. Great care must be taken not to let the junction touch the fused
substance. The crucible is now allowed to cool, and a reading of the
deflection taken every half-minute. When the substance is exactly at
its solidifying point—identical in general with the melting point—the
deflection remains stationary for several consecutive readings, owing
to the liberation of latent heat of fusion in sufficient quantity
to balance the loss by radiation. This stationary reading is noted
for each substance, and represents the deflection given when the hot
junction is at the temperature corresponding to the melting point, and
the cold junction or junctions at the temperature existing when the
observation is made. For melting the materials, a Davies furnace with
a large Teclu or Meker burner is convenient up to 850° C.; but to melt
the copper a blast lamp is requisite. The molten mass may be allowed to
cool in the furnace.
From these observations a calibration curve may be drawn either for
differences between hot and cold junctions, or for a steady temperature
of the cold junctions. Two sets of data are appended to illustrate the
procedure.
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