+Absorbed Radiation converted into Heat.+--The most common effect of
absorbed radiation is to raise the temperature of the absorbing body,
and so cause it to re-emit long heat-waves. As the usual arrangement
is for the absorbing body to be at a lower temperature than the
radiating one, the waves given out by the absorber are longer than
those given out by the radiator, and so the net result is the
transformation of shorter waves into longer ones. But we have seen by
Prévost's theory of exchanges that radiator and absorber are
interchangeable, and therefore we see that those waves which are
emitted by the absorber and absorbed by the radiator are re-emitted by
the latter as shorter waves.
The mechanism by means of which the waves are converted into heat in
the body is still a mystery. That the waves should cause the electrons
to vibrate is perfectly clear, but how the vibrations of the electrons
are converted into those vibrations of the atoms {58} and molecules
which constitute heat is still unsolved, and the reverse process is, of
course, equally puzzling.
The heating of the body and the consequent re-emission of heat-waves is
not, however, the only process which goes on. In a large number of
substances, waves are given out under the stimulus of other waves
without any heating of the body at all. In most of these cases the
emission stops as soon as the stimulating waves are withdrawn, and in
these cases the phenomenon has been called fluorescence. The name has
been derived from fluor spar, the substance which was first observed to
exhibit this peculiar emission of waves.
A familiar example of fluorescence is provided by paraffin-oil, which
glows with a blue light when it is illuminated with ordinary sunlight
or daylight. Perhaps the easiest way to view it is to project a narrow
beam of light through the paraffin-oil contained in a glass vessel and
view the oil in a direction perpendicular to the beam. The latter will
then show up a brilliant blue.
A water solution of sulphate of quinine, made acid by a few drops of
sulphuric acid, also exhibits a blue fluorescence, while a water
solution of æsculin (made by pouring hot water over some scraps of
horse-chestnut bark) shines with a brilliant blue light.
Some lubricating oils fluoresce with a green light, as does also a
solution in water of fluorescene, named thus because of its marked
fluorescence.
A solution of chlorophyll in alcohol, which can be readily prepared by
soaking green leaves in alcohol, shows a red fluorescence; uranium
glass--the canary glass of which small vases are very frequently {59}
made--exhibits a brilliant green fluorescence, as does also crystal
uranium nitrate.
It is found, on observing the spectrum of the fluorescent light, that a
fairly small range of waves is emitted showing a well-marked maximum of
intensity at a wave-length which is characteristic of the particular
fluorescing substance.
Public-domain text, read in full here on John Shaqi.
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