There also seems to be a limited range of waves which can induce this
fluorescence, and this range also depends upon the fluorescing
substance. As a rule, the inducing waves are shorter in length than
the induced fluorescence, but this rule has some very marked exceptions.
The fact that only a limited range of waves produces fluorescence
explains a noticeable characteristic of the phenomenon. If the
fluorescing solutions are at all strong the fluorescence is confined to
the region close to where the light enters the solution, thus showing
that the rays which are responsible for inducing the glow become
rapidly absorbed, whereas the remainder of the light goes on
practically unabsorbed.
+Phosphorescence.+--Sometimes the emission of the induced light
continues for some time after the inducing waves are withdrawn, and
then the phenomenon is termed phosphorescence, since phosphorus emits a
continuous glow without rise of temperature.
Sometimes the glow will continue for several hours after the exciting
rays have been cut off, a good example of this being provided by
Balmain's luminous paint, which is a sulphide of calcium. With other
substances the glow will only continue for a very small fraction of a
second, so that it is impossible to {60} say where fluorescence ends
and where phosphorescence begins.
In order to determine the duration of the glow in the case of these
small times, an arrangement consisting of two rotating discs, each of
which have slits in them, is set up. Through the slits in one of them
the substance is illuminated, and through the slits in the other the
substance is observed while the light is cut off. By adjusting the
position of the discs with regard to each other the slits may be made
to follow one another after greater or shorter intervals, and so the
time of observation can be made greater or smaller after the
illumination is cut off.
All the bodies which have been observed to exhibit phosphorescence are
solid.
+Theory of Fluorescence.+--It is fairly simple to imagine a mechanism
by which fluorescence might be brought about, as we might assume a
relation between the periods of oscillation of certain types of
electron in the substance and the period of the stimulating waves.
Thus resonance might occur, and the consequent vibrations of the
electrons would start a series of secondary waves.
If, however, we assume resonance, it is difficult to see why there is a
range of wave-lengths produced and another range of wave-lengths which
may produce them. We should have expected one definite wave-length or
a few definite ones producing one or a few definite wave-lengths in the
glow, while if a whole range of waves will produce the effect it is
difficult to see why all bodies do not exhibit the phenomenon.
Public-domain text, read in full here on John Shaqi.
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