When the phenomena of induced radio-activity, which will be discussed
later on, were made known, it seemed obvious that polonium, which only
shows the bismuth lines and whose activity diminishes with time, was not
a new element, but bismuth made active by the vicinity of radium in the
pitchblende. I am not sure that this opinion is correct. In the course
of my prolonged work on polonium, I have noted chemical effects, which I
have never observed either with ordinary bismuth or with bismuth made
active by radium. These chemical effects are, in the first place, the
extremely ready formation of insoluble compounds, of which I have spoken
above (especially basic nitrates), and, in the second place, the colour
and appearance of the precipitates obtained by adding water to the
nitric acid solution of bismuth containing polonium. These precipitates
are sometimes white, but more generally of a more or less vivid yellow,
verging on red.
The absence of lines other than those of bismuth does not necessarily
prove that the substance only contains bismuth, because bodies exist
whose spectrum reaction is scarcely visible.
It would be necessary to prepare a small quantity of bismuth containing
polonium in as concentrated a condition as possible, and to examine it
chemically, in the first place determining the atomic weight of the
metal. It has not yet been possible to carry out this research on
account of the difficulties of a chemical nature already mentioned.
If polonium were proved to be a new element, it would be no less true
that it cannot exist indefinitely in a strongly radio-active condition,
at least when extracted from the ore. There are therefore two aspects of
the question:—First, whether the activity of polonium is entirely
induced by the proximity of substances themselves radio-active, in which
case polonium would possess the faculty of acquiring atomic activity
permanently, a faculty which does not appear to belong to any substance
whatever; second, whether the activity of polonium is an inherent
property, which is spontaneously destroyed under certain conditions, and
persists under certain other conditions, such as those which exist in
the ore. The phenomenon of atomic activity induced by contact is still
so little understood, that we lack the ground on which to formulate any
opinion on the matter.
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