(NOTE.—A work has recently appeared on polonium by M. Marckwald. He
plunges a small rod of pure bismuth into a hydrochloric acid solution of
the bismuth extracted from the pitchblende residue. After some time the
rod becomes coated with a very active deposit, and the solution now
contains only inactive bismuth. M. Marckwald also obtains a very active
deposit by adding tin chloride to a hydrochloric acid solution of
radio-active bismuth. From this he concludes that the active element is
allied to tellurium, and gives it the name of _radiotellurium_. This
active substance of M. Marckwald seems identical with polonium, from its
behaviour, and from the easily absorbed rays it emits. The choice of a
new name for this substance is futile in the present state of the
question).
_Preparation of the Pure Chloride of Radium._
The method by which I extracted pure radium chloride from barium
chloride containing radium consists in first subjecting the mixture of
the chlorides to fractional crystallisation in pure water, then in water
to which hydrochloric acid has been added. The difference in solubility
of the two chlorides is thus made use of, that of radium being less
soluble than that of barium.
At the beginning of the fractionation, pure distilled water is used. The
chloride is dissolved, and the solution raised to boiling-point, and
allowed to crystallise by cooling in a covered capsule. Beautiful
crystals form at the bottom, and the supernatant, saturated solution is
easily decanted. If part of this solution be evaporated to dryness, the
chloride obtained is found to be about five times less active than that
which has crystallised out. The chloride is thus divided into two
portions, A and B—portion A being more active than portion B. The
operation is now repeated with each of the chlorides A and B, and in
each case two new portions are obtained. When the crystallisation is
finished, the less active fraction of chloride A is added to the more
active fraction of chloride B, these two having approximately the same
activity. Thus there are now three portions to undergo afresh the same
treatment.
The number of portions is not allowed to increase indefinitely. The
activity of the most soluble portion diminishes as the number increases.
When its activity becomes inconsiderable, it is withdrawn from the
fractionation. When the desired number of fractions has been obtained,
fractionation of the least soluble portion is stopped (the richest in
radium), and it is withdrawn from the remainder.
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