Uranium (containing a little carbon) 2·3 × 10⁻¹¹ amperes
Black oxide of uranium 2·6 „
Green „ „ 1·8 „
Acid uranic hydrate 0·6 „
Uranate of sodium 1·2 „
Uranate of potassium 1·2 „
Uranate of ammonia 1·3 „
Uranous sulphate 0·7 „
Sulphate of uranium and potassium 0·7 „
Acetate 0·7 „
Phosphate of copper and uranium 0·9 „
Oxysulphide of uranium 1·2 „
The interesting point in connection with these results is that some
specimens of pitchblende have four times the activity of the metal
uranium; chalcolite, the crystallized phosphate of copper and uranium,
is twice as active as uranium; and autunite, a phosphate of calcium and
uranium, is as active as uranium. From the previous considerations, none
of the substances should have shown as much activity as uranium or
thorium. In order to be sure that the large activity was not due to the
particular chemical combination, Mme Curie prepared chalcolite
artificially, starting with pure products. This artificial chalcolite
had the activity to be expected from its composition, viz. about 0·4 of
the activity of the uranium. The natural mineral chalcolite is thus five
times as active as the artificial mineral.
It thus seemed probable that the large activity of some of these
minerals, compared with uranium and thorium, was due to the presence of
small quantities of some very active substance, which was different from
the known bodies thorium and uranium.
This supposition was completely verified by the work of M. and Mme
Curie, who were able to separate from pitchblende by purely chemical
methods two active bodies, one of which in the pure state is over a
million times more active than the metal uranium.
This important discovery was due entirely to the property of
radio-activity possessed by the new bodies. The only guide in their
separation was the activity of the products obtained. In this respect
the discovery of these bodies is quite analogous to the discovery of
rare elements by the methods of spectrum analysis. The method employed
in the separation consisted in examining the relative activity of the
products after chemical treatment. In this way it was seen whether the
radio-activity was confined to one or another of the products, or
divided between both, and in what ratio such division occurred.
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