The activity of the specimens thus served as a basis of rough
qualitative and quantitative analysis, analogous in some respects to the
indication of the spectroscope. To obtain comparative data it was
necessary to test all the products in the dry state. The chief
difficulty lay in the fact that pitchblende is a very complex mineral,
and contains in varying quantities nearly all the known metals.
=12. Radium.= The analysis of pitchblende by chemical methods, using the
procedure sketched above, led to the discovery of two very active
bodies, polonium and radium. The name polonium was given to the first
substance discovered by Mme Curie in honour of the country of her birth.
The name radium was a very happy inspiration of the discoverers, for
this substance in the pure state possesses the property of
radio-activity to an astonishing degree.
Radium is extracted from pitchblende by the process used to separate
barium, to which radium is very closely allied in chemical
properties[17]. After the removal of other substances, the radium
remains behind mixed with barium. It can, however, be partially
separated from the latter by the difference in solubility of the
chlorides in water, alcohol, or hydrochloric acid. The chloride of
radium is less soluble than that of barium, and can be separated from it
by the method of fractional crystallization. After a large number of
precipitations, the radium can be freed almost completely from the
barium.
Both polonium and radium exist in infinitesimal quantities in
pitchblende. In order to obtain a few decigrammes of very active radium,
it is necessary to use several tons of pitchblende, or the residues
obtained from the treatment of uranium minerals. It is thus obvious that
the expense and labour involved in preparation of a minute quantity of
radium are very great.
M. and Mme Curie were indebted for their first working material to the
Austrian government, who generously presented them with a ton of the
treated residue of uranium materials from the State manufactory of
Joachimsthal in Bohemia. With the assistance of the Academy of Science
and other societies in France, funds were given to carry out the
laborious work of separation. Later the Curies were presented with a ton
of residues from the treatment of pitchblende by the Société Centrale de
Produits Chimiques of Paris. The generous assistance afforded in this
important work is a welcome sign of the active interest taken in these
countries in the furthering of purely scientific research.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account