The rough concentration and separation of the residues was performed in
the chemical works, and there followed a large amount of labour in
purification and concentration. In this manner, the Curies were able to
obtain a small quantity of radium which was enormously active compared
with uranium. No definite results have yet been given on the activity of
pure radium, but the Curies estimate that it is about one million times
that of uranium, and may possibly be still higher. The difficulty of
making a numerical estimate for such an intensely active body is very
great. In the electric method, the activities are compared by noting the
relative strength of the maximum or saturation current between two
parallel plates, on one of which the active substance is spread. On
account of the intense ionization of the gas between the plates, it is
not possible to reach the saturation current unless very high voltages
are applied. Approximate comparisons can be made by the use of metal
screens to cut down the intensity of the radiations, if the proportion
of the radiation transmitted by such a screen has been determined by
direct experiment on impure material of easily measurable activity. The
value of the activity of radium compared with that of uranium will
however vary to some extent according to which of the three types of
rays is taken as a basis of comparison.
It is thus difficult to control the final stages of the purification of
radium by measurements of its activity alone. Moreover the activity of
radium immediately after its preparation is only about one-fourth of its
final value; it gradually rises to a maximum after the radium salt has
been kept in the dry state for about a month. For control experiments in
purification, it is advisable to measure the initial rather than the
final activity.
Mme Curie has utilized the coloration of the crystals of radiferous
barium as a means of controlling the final process of purification. The
crystals of salts of radium and barium deposited from acid solutions are
indistinguishable by the eye. The crystals of radiferous barium are at
first colourless, but, in the course of a few hours, become yellow,
passing to orange and sometimes to a beautiful rose colour. The rapidity
of this coloration depends on the amount of barium present. Pure radium
crystals do not colour, or at any rate not as rapidly as those
containing barium. The coloration is a maximum for a definite proportion
of radium, and this fact can be utilized as a means of testing the
amount of barium present. When the crystals are dissolved in water the
coloration disappears.
Giesel[18] has observed that pure radium bromide gives a beautiful
carmine colour to the Bunsen flame. If barium be present in any
quantity, only the green colour due to barium is observed, and a
spectroscopic examination shows only the barium lines. This carmine
coloration of the Bunsen flame is a good indication of the purity of the
radium.
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