(3) Precipitation by sulphuretted hydrogen in a very acid hydrochloric
acid solution. The precipitated sulphides are much more active than the
salt which remains in solution.
For concentration of the active substance Mme Curie[33] has made use of
method (2). The process is, however, very slow and tedious, and is made
still more complicated by the tendency to form precipitates insoluble
either in strong or weak acids. After a large number of fractionations,
a small quantity of matter was obtained, enormously active compared with
uranium. On examination of the substance spectroscopically, only the
bismuth lines were observed. A spectroscopic examination of the active
bismuth by Demarçay and by Runge and Exner has led to the discovery of
no new lines. On the other hand Sir William Crookes[34] states that he
found one new line in the ultra-violet, while Berndt[35], working with
polonium of activity 300, observed a large number of new lines in the
ultra-violet. These results await further confirmation.
The polonium prepared by Mme Curie differs from the other radio-active
bodies in several particulars. In the first place the radiations include
only very easily absorbable rays. The two penetrating types of radiation
given out by uranium, thorium, and radium are absent. In the second
place the activity does not remain constant, but diminishes continuously
with the time. Mme Curie states that different preparations of polonium
had somewhat different rates of decay. In some cases, the activity fell
to half value in about six months, and in others, about half value in
eleven months.
=20.= The gradual diminution of the activity of polonium with time
seemed at first sight to differentiate it from such substances as
uranium and radium, the activity of which appeared fairly permanent.
This difference in behaviour is, however, one of degree rather than of
kind. We shall show later that there is present in pitchblende a number
of radio-active substances, the activity of which is not permanent. The
time taken for these bodies to lose half of their activity varies in
different cases from a few seconds to several hundreds of years. In
fact, this gradual loss of activity is an essential feature of our
theory of regarding the phenomena of radio-activity. No radio-active
substance, left to itself, can continue to radiate indefinitely; it must
ultimately lose its activity. In the case of bodies like uranium and
radium, the loss of activity is so slow that no sensible alteration has
been observed over a period of several years, but it can be deduced
theoretically that the activity of radium will eventually decrease to
half value in a period of about 1000 years, while in the case of a
feebly radio-active substance like uranium, more than a 100 million
years must elapse before the diminution of the activity becomes
appreciable.
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