It may be of interest here to consider briefly the suggestions advanced
at various times to account for the temporary character of the activity
of polonium. Its association with bismuth led to the view that polonium
was not a new active substance, but merely radio-active bismuth, that
is, bismuth which in some way had been made active by admixture with
radio-active bodies. It was known that a body placed in the vicinity of
thorium or radium became temporarily active. The same action was
supposed to take place when inactive matter was in solution with active
matter. The non-active matter was supposed to acquire activity by
“induction,” as it was called, in consequence of its intimate contact
with the active material.
There is no proof, however, that such is the case. The evidence points
rather to the conclusion that the activity is due, not to an alteration
of the inactive body itself, but to an admixture with it of a very small
quantity of intensely active matter. This active matter is present in
pitchblende and is separated with the bismuth but differs from it in
chemical properties.
The subject cannot be considered with advantage at this stage, but will
be discussed later in detail in chapter XI. It will there be shown that
polonium, that is, the radio-active constituent mixed with the bismuth,
is a distinct chemical substance, which is allied in chemical properties
to bismuth, but possesses some distinct analytical properties which
allow of a partial separation from it.
The polonium, if obtained in a pure state, should initially be several
hundred times as active as pure radium. This activity, however, is not
permanent; it decays with the time, falling to half value in about six
months.
The absence of any new lines in the spectrum of radio-active bismuth is
to be expected, for, even in the most active bismuth prepared, the
active matter exists in a very small proportion.
=21.= The discussion of the nature of polonium was renewed by the
discovery of Marckwald[36] that a substance similar to polonium can be
separated from pitchblende; the activity of this substance, he stated,
did not decay appreciably with the time. The method of separation from
the bismuth chloride solution, obtained from uranium residues, was very
simple. A rod of bismuth or antimony, dipped in the active solution,
rapidly became coated with a black deposit which was intensely active.
This process was continued until the whole of the activity was removed
from the solution. The active deposit gave out only easily absorbed
rays, and in that respect resembled the polonium of Mme Curie.
The active substance was found to consist mainly of tellurium, and for
this reason Marckwald gave it the name of radio-tellurium. In later
work, however, Marckwald[37] has shown that the active constituent has
no connection with tellurium, but can always be separated completely
from it by a simple chemical process.
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