The variation with time of the residual activity measured by the α rays
will first be considered. A platinum plate was exposed in the presence
of the radium emanation for seven days. The amount of emanation
initially present was equal to that obtained from about 3 milligrams of
pure radium bromide. The plate immediately after removal gave a
saturation-current, measured between parallel plates by a galvanometer,
of 1·5 × 10⁻⁷ ampere. Some hours after removal, the activity decayed
according to an exponential law with the time, falling to half value in
28 minutes. Three days after removal the active plate gave a
saturation-current, measured by an electrometer, of 5 × 10⁻¹³ ampere;
_i.e._ ¹⁄₃₀0,000 of the initial activity. The activity was observed to
increase steadily with the time. The results are shown in Fig. 93, where
the time is reckoned from the middle of the time of exposure to the
emanation.
The curve is initially nearly a straight line passing through the
origin. The activity increases with the time for the interval of eight
months over which the observations have extended. The latter portions of
the curve, however, fall below the tangent to the curve drawn through
the origin, showing that the activity is not increasing proportionately
with the time.
The active deposit, obtained in a different manner, has been examined
for a still longer period. The emanation from 30 milligrams of radium
bromide was condensed in a glass tube and then sealed. After a month’s
interval, the tube was opened and dilute sulphuric acid introduced. The
acid dissolved off the active deposit in the tube and on driving off the
acid by heat, a radio-active residue was obtained. The activity of this
residue, measured by the α rays, steadily increased for a period of 18
months, but the curve of variation of activity with time plotted as in
Fig. 93 tends to become more flattened, and is obviously approaching a
maximum value.
[Illustration: Fig. 93.]
The explanation of this curve will be considered later in section 236.
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