For a given intensity of radiation, the saturation P.D. decreases
rapidly with the lowering of the pressure of the gas. This is due to two
causes operating in the same direction, viz. a decrease in the intensity
of the ionization and an increase in the velocity of the ions. The
ionization varies directly as the pressure, while the velocity varies
inversely as the pressure. This will obviously have the effect of
causing more rapid saturation, since the rate of recombination is slower
and the time taken for the ions to travel between the electrodes is
less.
The saturation curves observed for the gases hydrogen and carbon
dioxide[49] are very similar in shape to those obtained for air. For a
given intensity of radiation, saturation is more readily obtained in
hydrogen than in air, since the ionization is less than in air while the
velocity of the ions is greater. Carbon dioxide on the other hand
requires a greater P.D. to produce saturation than does air, since the
ionization is more intense and the velocity of the ions less than in
air.
=29.= Townsend[50] has shown that, for low pressures, the variation of
the current with the voltage is very different from that observed at
atmospheric pressure. If the increase of current with the voltage is
determined for gases, exposed to Röntgen rays, at a pressure of about 1
mm. of mercury, it is found that for small voltages the ordinary
saturation curve is obtained; but when the voltage applied increases
beyond a certain value, depending on the pressure and nature of the gas
and the distance between the electrodes, the current commences to
increase slowly at first but very rapidly as the voltage is raised to
the sparking value. The general shape of the current curve is shown in
Fig. 5.
[Illustration: Fig. 5.]
The portion _OAB_ of the curve corresponds to the ordinary saturation
curve. At the point _B_ the current commences to increase. This increase
of current has been shown to be due to the action of the negative ions
at low pressures in producing fresh ions by collision with the molecules
in their path. The increase of current is not observed in air at a
pressure above 30 mms. until the P.D. is increased nearly to the value
required to produce a spark. This production of ions by collision is
considered in more detail in section 41.
=30. Rate of recombination of the ions.= A gas ionized by the radiation
preserves its conducting power for some time after it is removed from
the presence of the active body. A current of air blown over an active
body will thus discharge an electrified body some distance away. The
duration of this after conductivity can be examined very conveniently in
an apparatus similar to that shown in Fig. 6.
[Illustration: Fig. 6.]
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