The negative and positive ions certainly differ in size, and this
difference becomes very pronounced for low pressures of the gas. At
atmospheric pressure, the negative ion, produced by the action of
ultra-violet light on a negatively charged body, is of the same size as
the ion produced by X rays, but at low pressures J. J. Thomson has shown
that it is identical with the corpuscle or electron, which has an
apparent mass of about ¹⁄₁₀₀₀ of the mass of the hydrogen atom. A
similar result has been shown by Townsend to hold for the negative ion
produced by X rays at a low pressure. It appears that the negative ion
at low pressure sheds its attendant cluster. The result of Langevin,
that the velocity of the negative ion increases more rapidly with the
diminution of pressure than that of the positive ion, shows that this
process of removal of the cluster is quite appreciable at a pressure of
10 mms. of mercury.
We must suppose that the process of ionization in gases consists in a
removal of a negative corpuscle or electron from the molecule of the
gas. At atmospheric pressure this corpuscle immediately becomes the
centre of an aggregation of molecules which moves with it and _is_ the
negative ion. After removal of the negative ion the molecule retains a
positive charge, and probably also becomes the centre of a cluster of
new molecules.
The terms electron and ion as used in this work may therefore be defined
as follows:—
The _electron_ or _corpuscle_ is the body of smallest mass yet known to
science. It carries a negative charge of value 3·4 × 10⁻¹⁰ electrostatic
units. Its presence has only been detected when in rapid motion, when,
for speeds up to about 10¹⁰ cms. a second, it has an apparent mass _m_
given by _e_/_m_ = 1·86 × 10⁷ electromagnetic units. This apparent mass
increases with the speed as the velocity of light is approached (see
section 82).
The ions which are produced in gases at ordinary pressure have an
apparent size, as determined from their rates of diffusion, large
compared with the molecule of the gas in which they are produced. The
negative ion consists of an electron with a cluster of molecules
attached to and moving with it; the positive ion consists of a molecule
from which an electron has been expelled, with a cluster of molecules
attached. At low pressures under the action of an electric field the
electron does not form a cluster. The positive ion is always atomic in
size, even at low pressures of the gas. Each of the ions carries a
charge of value 3·4 × 10⁻¹⁰ electrostatic units.
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