=41. Ions produced by collision.= The greater part of the radiation from
the radio-active bodies consists of a stream of charged particles
travelling with great velocity. In this radiation, the α particles,
which cause most of the ionization observed in the gas, consist of
positively charged bodies projected with a velocity about one-tenth the
velocity of light. The β rays consist of negatively charged particles,
which are identical with the cathode rays generated in a vacuum tube,
and travel with a speed about one-half the velocity of light (chapter
IV.). Each of these projected particles, in virtue of its great kinetic
energy, sets free a large number of ions by collision with the gas
molecules in its path. No definite experimental evidence has yet been
obtained of the number of ions produced by a single particle, or of the
way in which the ionization varies with the speed, but there is no doubt
that each projected body gives rise to many thousand ions in its path
before its energy of motion is destroyed.
It has already been mentioned (section 29) that at low pressures ions
moving under the action of an electric field are able to produce fresh
ions by collision with the molecules of the gas. At low pressures the
negative ion is identical with the electron set free in a vacuum tube,
or emitted by a radio-active substance.
The mean free path of the ion is inversely proportional to the pressure
of the gas. Consequently, if an ion moves in an electric field, the
velocity acquired between collisions increases with diminution of the
pressure. Townsend has shown that fresh ions are occasionally produced
by collision when the negative ion moves freely between two points
differing in potential by 10 volts. If the difference be about _V_ = 20
volts, fresh ions arise at each collision[73].
Now the energy _W_, acquired by an ion of charge _e_ moving freely
between two points at a difference of potential _V_, is given by
_W_ = _Ve_.
Taking _V_ = 20 volts = ²⁰⁄₃₀₀ E. S. units, and _e_ = 3·4 × 10⁻¹⁰, the
energy _W_ required in the case of a negative ion to produce an ion by
collision is given by
_W_ = 2·3 × 10⁻¹¹ ergs.
The velocity _u_ acquired by the ion of mass _m_ just before a collision
is given by
1
--- _mu²_ = _Ve_,
2
and
$$ u = \sqrt{\frac{2Ve}{m}} $$
Now _e_/_m_ = 1·86 × 10⁷ electromagnetic units for the electron at slow
speeds (section 82).
Taking _V_ = 20 volts, we find that
_u_ = 2·7 × 10⁸ cms. per sec.
This velocity is very great compared with the velocity of agitation of
the molecules of the gas.
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