Researches Chemical and Philosophical; Chiefly concerning nitrous oxide: or dephlogisticated nitrous air and its respirationDavy, Humphry, Sir
Science
Researches Chemical and Philosophical; Chiefly concerning nitrous oxide: or dephlogisticated nitrous air and its respiration
Davy, Humphry, Sir
Nitrous oxide
It is probable that nitrous oxide may be combined with ammoniac,
by means of double affinity. Perhaps sulphate of ammoniac and the
combination of potash with nitrous oxide mingled together in solution,
would be converted into sulphate of potash and the compound of nitrous
oxide, and ammoniac.
X. _Probability of forming Compounds of Nitrous Oxide and the Alkaline
Earths._
I attempted to combine nitrous oxide with lime and strontian, by
exposing sulphites of lime and strontian with excess of earth, to
nitrous gas; but this process did not succeed: the diminution took
place so slowly as to destroy all hopes of gaining any results in
a definite time. Sulphite of potash is decomposable by barytes,
strontian, and lime;[164] consequently it was impossible to employ this
substance to effect the combination.
As the dry sulphures, when well made, convert nitrous gas into nitrous
oxide, it is probable that the union of the earths with nascent nitrous
oxide may be effected by exposing nitrous gas to their sulphures,
containing an excess of earth.
[164] See the above mentioned elaborate memoir of Fourcroy and
Vauquelin.
Perhaps the combination of nitrous oxide with strontian may be effected
by introducing the combination of potash and nitrous oxide into
strontian lime water.
It is probable that nitrous oxide may be combined with clay and
magnesia, by exposing these bodies, mingled with sulphite of potash or
soda, to nitrous gas.
XI. _Additional Observations on the combinations of Nitrous Oxide with
the Alkalies._
A desire to complete physiological investigations relating to nitrous
oxide, has hitherto prevented me from pursuing to a greater extent, the
experiments on the combination of this substance with the alkalies, &c.
As soon as an opportunity occurs, I purpose to resume the subject.
The observations detailed in the foregoing sections are sufficient to
show that nitrous oxide is capable of entering into intimate union
with the fixed alkalies: and as the compounds formed by this union
are insoluble in alcohol, decomposable by the acids, and heat, and
possessed of peculiar properties, they ought to be considered as a new
class of saline substances.
If it is thought proper, on a farther investigation of their
properties, to signify them by specific names, they may, according to
the usually adopted fashion of nomenclature, be called _nitroxis_:
thus the _nitroxi of potash_ would signify the salt formed by the
combination of nitrous oxide with potash.
Future experiments must determine the different affinities of nitrous
oxide for the alkalies, and alkaline earths.
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