Researches on Cellulose, 1895-1900Cross, C. F. (Charles Frederick)
Science
Researches on Cellulose, 1895-1900
Cross, C. F. (Charles Frederick)
Cellulose
In the use of the word 'normal' as applied to a 'bleached' cotton, we
have further to show in what respects the sulphocarbonate reaction
differentiates the bleached or purified cotton cellulose from the raw
product. The following experiments may be cited: Specimens of American
and Egyptian cottons in the raw state, freed from mechanical, i.e.
non-fibrous, impurities, were treated with a mercerising alkali, and the
alkali-cotton subsequently exposed to carbon disulphide. The product of
reaction was further treated as in the preparation of the ordinary
solution; but in place of the usual solution, structureless and
homogeneous, it was observed to retain a fibrous character, and the
fibres, though enormously swollen, were not broken down by continued
vigorous stirring. After large dilution the solutions were filtered, and
the fibres then formed a gelatinous mass on the filters. After
purification, the residue was dried and weighed. The American cotton
yielded 90.0 p.ct., and the Egyptian 92.0 p.ct. of its substance in the
form of this peculiar modification. The experiment was repeated,
allowing an interval of 24 hours to elapse between the conversion into
alkali-cotton and exposure of this to the carbon disulphide. The
quantitative results were identical.
There are many observations incidental to chemical treatments of cotton
fabrics which tend to show that the bleaching process produces other
effects than the mere removal of mechanical impurities. In the
sulphocarbonate reaction the raw cotton, in fact, behaves exactly as a
compound cellulose. Whether the constitutional difference between raw
and bleached cotton, thus emphasised, is due to the group of components
of the raw cotton, which are removed in the bleaching process, or to
internal constitutional changes determined by the bleaching treatments,
is a question which future investigation must decide.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account