Researches on Cellulose, 1895-1900Cross, C. F. (Charles Frederick)
Science
Researches on Cellulose, 1895-1900
Cross, C. F. (Charles Frederick)
Cellulose
Similarly the cellulose in reverting to the solid form from these
'degraded' solutions presents a proportionate loss of cohesion and
aggregating power expressed by the inferior strength and elasticity of
the products. Hence, in the practical applications of the product where
the latter properties are of first importance, it is necessary to adopt
normal standards, such as above indicated, and to carefully regulate all
the conditions of treatment in each of the two main stages of reaction,
so that a product of any desired character may be invariably obtained.
Incidentally to these investigations a number of observations have been
made on the alkali-cellulose (cotton) after prolonged storage in closed
vessels. It is well known that starch undergoes hydrolysis in contact
with aqueous alkalis of a similar character to that determined by acids
[Bechamp, Annalen, 100, 365]. The recent researches of Lobry de Bruyn
[Rec. Trav. Chim. 14, 156] upon the action of alkaline hydrates in
aqueous solution on the hexoses have established the important fact of
the resulting mobility of the CO group, and the interchangeable
relationships of typical aldoses and ketoses. It was, therefore, not
improbable that profound hydrolytic changes should occur in the
cellulose molecule when kept for prolonged periods as alkali-cellulose.
We may cite an extreme case. A series of products were examined after
12-18 months' storage. They were found to contain only 3-5 p.ct.
'soluble carbohydrates'; these were precipitated by Fehling's solution
but without reduction on boiling. They were, therefore, of the cellulose
type. On acidifying with sulphuric acid and distilling, traces only of
volatile acid were produced. It is clear, therefore, that the change of
molecular weight of the cellulose, the disaggregation of the undoubtedly
large molecule of the original 'normal' cellulose--which effects are
immediately recognised in the viscose reactions of such products--are of
such otherwise limited character that they do not affect the
constitution of the unit groups. We should also conclude that the
cellulose type of constitution covers a very wide range of minor
variations of molecular weight or aggregation.
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