Researches on Cellulose, 1895-1900Cross, C. F. (Charles Frederick)
Science
Researches on Cellulose, 1895-1900
Cross, C. F. (Charles Frederick)
Cellulose
_Wood gum_, from beech wood, gave a tetranitrate (C_{10} formula)
insoluble in all the usual solvents for this group of esters.
The authors point out in conclusion that the conditions of instability
and decomposition of the nitrates of the monose-triose series are
exactly those noted with the cellulose nitrates as directly prepared and
freed from residues of the nitrating acids. They also lay stress upon
the superior stability of the nitrates of the anhydrides, especially of
the ketoses.
NITRATED CARBOHYDRATES AS FOOD MATERIAL FOR MOULDS.
THOMAS BOKORNY (Chem. Zeit., 1896, 20, 985-986).
(p. 38) Cellulose trinitrate (nitrocellulose) will serve as a food
supply for moulds when suspended in distilled water containing the
requisite mineral matter and placed in the dark. The growth is rapid,
and a considerable quantity of the vegetable growth accumulates round
the masses of cellulose nitrate, but no growth is observed if mineral
matter is absent. Cellulose itself cannot act as a food supply, and it
seems probable that if glycerol is present cellulose nitrate is no
longer made use of.
NITRATION OF CELLULOSE, HYDROCELLULOSE, AND OXYCELLULOSE.
LEO VIGNON (Compt. rend., 1898, 126, 1658-1661).
(p. 38) Repeated treatment of cellulose, hydrocellulose, and
oxycellulose with a mixture of sulphuric and nitric acids in large
excess, together with successive analyses of the compounds produced,
showed that the final product of the reaction corresponded, in each
case, with the fixation of 11 NO groups by a molecule containing 24
atoms of carbon. On exposure to air, nitrohydrocellulose becomes yellow
and decomposes; nitro-oxycellulose is rather more stable, whilst
nitrocellulose is unaffected. The behaviour of these nitro-derivatives
with Schiff's reagent, Fehling's solution, and potash show that all
three possess aldehydic characters, which are most marked in the case of
nitro-oxycellulose. The latter also, when distilled with hydrochloric
acid, yields a larger proportion of furfuraldehyde than is obtained from
nitrocellulose and nitrohydrocellulose.
* * * * *
~CELLULOSE NITRATES-EXPLOSIVES.~
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