Researches on Cellulose, 1895-1900Cross, C. F. (Charles Frederick)
Science
Researches on Cellulose, 1895-1900
Cross, C. F. (Charles Frederick)
Cellulose
(p. 38) The uses of the cellulose nitrates as a basis for explosives are
limited by their fibrous character. The conversion of these products
into the structureless homogeneous solid or semi-solid form has the
effect of controlling their combustion. The use of nitroglycerin as an
agent for this purpose gives the curious result of the admixture of two
high or blasting explosives to produce a new explosive capable of
extended use for military purposes. The leading representatives of this
class of propulsive explosives, or 'smokeless powders' are ballistite
and cordite, the technology of which will be found fully discussed in
special manuals of the subject. Since the contribution of these
inventions to the development of cellulose chemistry does not go beyond
the broad, general facts above mentioned, we must refer the reader for
technical details to the manuals in question.
There are, however, other means of arriving at structureless cellulose
nitrates. One of these has been recently disclosed, and as the results
involve chemical and technical points of novelty, which are dealt with
in a scientific communication, we reproduce the paper in question,
viz.:--
A RE-INVESTIGATION OF THE CELLULOSE NITRATES.
A. LUCK and C. F. CROSS (J. Soc. Chem. Ind., 1900).
The starting-point of these investigations was a study of the nitrates
obtained from the structureless cellulose obtained from the
sulphocarbonate (viscose). This cellulose in the form of a fine meal was
treated under identical conditions with a sample of pure cotton
cellulose, viz. digested for 24 hours in an acid mixture containing in
100 parts HNO_{3}--24 : H_{2}SO_{4}--70 : H_{2}O--6: the proportion of
acid to cellulose being 60 : 1--. After careful purification the
products were analysed with the following results:
Soluble in
Nitrogen Ether alcohol
Fibrous nitrate 13.31 4.3 p.ct.
Structureless nitrate 13.35 5.6 "
Examined by the 'heat test' (at 80 deg.) and the 'stability test' (at 135 deg.)
they exhibited the usual instability, and in equal degrees. Nor were the
tests affected by exhaustive treatment with ether, benzene, and alcohol.
From this it appears that the process of solution as sulphocarbonate and
regeneration of the cellulose, though it eliminates certain constituents
of an ordinary bleached cellulose, which might be expected to cause
instability, has really no effect in this direction. It also appears
that instability may be due to by-products of the esterification process
derived from the cellulose itself.
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