Researches on Cellulose, 1895-1900Cross, C. F. (Charles Frederick)
Science
Researches on Cellulose, 1895-1900
Cross, C. F. (Charles Frederick)
Cellulose
a certain solvent action, and on adding an equal bulk of water, the
dissolved nitrate for the most part is precipitated, at the same time
that the undissolved but disintegrated and swollen product undergoes
further changes in the direction of increase of hardness and density.
The product being now collected on a filter, freed from acetone by
washing with water and dried, is a hard and dense powder the fineness of
which varies according to the attendant conditions of treatment. With
the main product in certain cases there is found associated a small
proportion of nitrate retaining a fibrous character, which may be
separated by means of a fine sieve. On examining such a residue, we
found it to contain only 5.6 p.ct. N, and as it was insoluble in strong
acetone, it may be regarded as a low nitrate or a mixture of such with
unaltered cellulose. Confirming this we found that the product passing
through the sieve showed an increase of nitrogen to 13.43 p.ct. from the
13.31 p.ct. in the original. Tested by the heat test (50 minutes) and
stability test (no fumes after 100 minutes), we found the products to
have the characteristics previously noticed.
It is clear, therefore, that this specifically regulated action of
acetone produces the effects (a) of disintegration, and (b)
stabilisation. It remains to determine whether the latter effect was
due, as might be supposed, to the actual elimination of a compound or
group of compounds present in the original nitrate, and to be regarded
as the effective cause of instability. It is to be noted first that as a
result of the treatment with the diluted acetone and further dilution
after the specific action is completed, collecting the disintegrated
product on a filter and washing with water, the loss of weight sustained
amounts to 3 to 4 p.ct. This loss is due, therefore, to products
remaining dissolved in the filtrate--that is to say, in the much diluted
acetone. These filtrates are in fact opalescent from the presence of a
portion of nitrate in a colloidal (hydrated) form. On distilling off the
acetone, a precipitation is determined. The precipitates are nitrates of
variable composition, analysis showing from 9 to 12 p.ct. of nitric
nitrogen. The filtrate from these precipitates containing only
fractional residues of acetone still shows opalescence. On
long-continued boiling a further precipitation is determined, the
filtrates from which are clear. It was in this final clear filtrate that
the product assumed to cause the instability of the original nitrate
would be present. The quantity, however, is relatively so small that we
have only been able to obtain and examine it as residue from evaporation
to dryness. An exhaustive qualitative examination established a number
of negative characteristics, with the conclusion that the products were
not direct derivatives of carbohydrates nor aromatic compounds. On the
other hand the following positive points resulted. Although the original
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