Researches on Cellulose, 1895-1900Cross, C. F. (Charles Frederick)
Science
Researches on Cellulose, 1895-1900
Cross, C. F. (Charles Frederick)
Cellulose
diluted acetone extract was neutral to test papers, yet the residue was
acid in character. It contained combined nitric groups, fused below 200 deg.
giving off acid vapours, and afterwards burning with a smoky flame. On
adding lead acetate to the original clear solution, a well-marked
precipitation was determined. The lead compounds thus isolated are
characteristic. They have been obtained in various ways and analysed.
The composition varies with the character of the solution in which the
lead compound is formed. Thus in the opalescent or milky solutions in
which a proportion of cellulose nitrate is held in solution or
semi-solution by the acetone still present, the lead acetate causes a
dense coagulation. The precipitates dried and analysed showed 16-20
p.ct. PbO and 11-9 p.ct. N. It is clear that the cellulose nitrates are
associated in these precipitates with the lead salts of the acid
compounds in question. When the latter are obtained from clear
solutions, i.e. in absence of cellulose nitrates, they contain 60-63
p.ct. PbO and 3.5 p.ct. N (obtained as NO).
In further confirmation of the conclusion from these results, viz. that
the nitrocelluloses with no tendency to combine with PbO are associated
with acid products or by-products of the ester reaction combining with
the oxide, the lead reagent was allowed to react in the presence of 90
p.ct. acetone. Water was added, the disintegrated mass collected, washed
with dilute acetic acid, and finally with water. Various estimations of
the PbO fixed in this way have given numbers varying from 2 to 2.5 p.ct.
Such products are perfectly stable. This particular effect of
stabilisation appears, therefore, to depend upon the combination of
certain acid products present in ordinary nitrocelluloses with metallic
oxides. In order to further verify this conclusion, standard specimens
of cellulose nitrates have been treated with a large number of metallic
salts under varying conditions of action. It has been finally
established (1) that the effects in question are more particularly
determined by treatment with salts of lead and zinc, and (2) that the
simplest method of treatment is that of boiling the cellulose nitrates
with dilute aqueous solutions of salts of these metals, preferably the
acetates. The following results may be cited, obtained by boiling a
purified 'service' guncotton (sample C) with a 1 p.ct. solution of lead
acetate and of zinc acetate respectively. After boiling 60 minutes the
nitrates were washed free from the soluble metallic salts, dried and
tested.
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