Science in Short ChaptersWilliams, W. Mattieu (William Mattieu)
Science
Science in Short Chapters
Williams, W. Mattieu (William Mattieu)
Science
This brings us to a subject of the highest and widest philosophical
and practical importance. I refer to the antagonism between the force
of heat and that of chemical combination, to which the French chemists
have given the name “dissociation.” Having myself been unable to find
any satisfactory English account of this subject at a time when it had
already been well treated by French and German authors, in the form of
published lectures and cyclopædia articles, I assume that others may
have encountered a similar difficulty, and therefore dwell rather more
fully upon this part of my present summary.
It appears that all chemical compounds may be decomposed by heat, and
that, at a given pressure, there is a definite and special temperature
at which the decomposition of each compound is effected. For the
absolute and final establishment of the universality of this law
further investigations are necessary, actual investigations having
established it as far as they have gone, but these have not been
exhaustive.
There appears to be a remarkable analogy between dissociation and
evaporation. When a liquid is vaporized, a certain amount of heat is
“rendered latent,” and this quantity varies with the liquid and with
the pressure, but is definite and invariable for each liquid at a given
pressure. In like manner, when a compound is dissociated, a certain
amount of heat is “rendered latent,” or converted into dissociating
force, and this varies with each compound and with the pressure, but
is definite and invariable for each compound at a given pressure.
Further, when condensation occurs, an amount of heat is evolved, as
temperature, exactly equal to that which was rendered latent in the
evaporation of the same substance under the same pressure; and, in like
manner, when chemical re-combination of dissociated elements occurs, an
amount of heat is evolved, as temperature, exactly equal to that which
disappeared when the compound was dissociated by heat _alone_ under
the same pressure.
According to the recently adopted figures of M. Deville, the
temperature at which the vapor of water becomes dissociated under
ordinary atmospheric pressure is 2800° C., and the, quantity of heat
which disappears, as temperature, in the course of dissociation is 2153
_calorics_, _i.e._, sufficient to raise 2153 times its own weight of
_liquid_ water 1° C.; but, as the specific heat of aqueous vapor is
to that of liquid water as 0·475 to 1, that latent heat expressed in
the temperature it would have given to aqueous vapor is = 4532° C., or
8158° F.
In order to render the analogy between the ebullition and dissociation
of water more evident and intelligible, I will state it as follows:—
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